Lithium bromide, anhydrous

• Catalog No.: 13408
• CAS Number: 7550-35-8
• M. F.: BrLi
• M. W.: 86.845
• Purity: 99% min

SYNONYMS

• Title: 无水溴化锂
• IUPAC name: lithium(1+) ion bromide
• IUPAC Traditional name: lithium(1+) ion bromide

DATABASE IDS

• MDL Number: MFCD00011077
• Merck Index: 145526
• CAS Number: 7550-35-8
• EC Number: 231-439-8

PROPERTIES

• Purity: 99% min
• Apperance: Crystalline
• Boiling Point: 1265°C
• Density: 3.464
• Melting Point: 550°C
• Solubility: Very soluble in water and alcohol. Soluble in methanol, acetone, and glycol. Slightly soluble in pyridine
• GHS Hazard statements: H302-H315-H319
• European Hazard Symbols: X
• GHS Precautionary statements: P280-P305+P351+P338-P302+P352-P321-P362-P501A
• Risk Statements: 22-36/38
• RTECS: OJ5755000
• Safety Statements: 26-36/37-60
• Storage Warning: Hygroscopic
• TSCA Listed: 是

REFERENCES

• For use in dehydrohalogenation reactions, see Lithium carbonate, 13418. For use in the Horner-Wadsworth-Emmons olefination reaction, see Lithium chloride, A10531, and Triethylamine, A12646. Catalyzes the solvent-free Knoevenagel condenastion of active methylene compounds with aldehydes and ketones: J. Chem. Soc., Perkin 1, 959 (1996). Chemoselective catalyst for the dithioacetalization of aromatic and ɑ?-unsaturated aldehydes under neutral conditions: Synthesis, 58 (1999). Efficient catalyst for the ring-opening of epoxides by amines at room temperature: Eur. J. Org. Chem., 3597 (2004). For a brief feature on uses in synthesis, see: Synlett, 1197 (2005).