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85017-82-9 molecular structure
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lithium(1+) ion bromide

ChemBase ID: 103382
Molecular Formular: BrLi
Molecular Mass: 86.845
Monoisotopic Mass: 85.93434155
SMILES and InChIs

SMILES:
[Li+].[Br-]
Canonical SMILES:
[Li+].[Br-]
InChI:
InChI=1S/BrH.Li/h1H;/q;+1/p-1
InChIKey:
AMXOYNBUYSYVKV-UHFFFAOYSA-M

Cite this record

CBID:103382 http://www.chembase.cn/molecule-103382.html

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NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
lithium(1+) ion bromide
IUPAC Traditional name
lithium(1+) ion bromide
LithoTab bromide
Synonyms
Lithium bromide
Lithium bromide, ultra dry
Lithium bromide hydrate, Puratronic®
LITHIUM BROMIDE
Lithium bromide solution
Lithium bromide, anhydrous
溴化锂
溴化锂, 超干
溴化锂,超干
溴化锂水合物, Puratronic®
溴化锂 溶液
无水溴化锂
溴化锂, 无水
CAS Number
85017-82-9
7550-35-8
EC Number
231-439-8
MDL Number
MFCD00149763
MFCD00011077
Merck Index
145526
PubChem SID
162090938
24852672
24866863
24868516
24853301
24865751
24882221
PubChem CID
82050
Chemspider ID
74049
Unique Ingredient Identifier
864G646I84
Wikipedia Title
Lithium_bromide

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
LogD (pH = 5.5) 0.0  LogD (pH = 7.4) 0.0 
Log P 0.0  Molar Refractivity 0.0 cm3
Polarizability 1.7969184 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five true 
Acid pKa 3.09 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Solubility
145 g/100 mL (4 °C)
166.7 g/100 mL (20 °C)
254 g/100 mL (90 °C) in water
expand Show data source
soluble in methanol, ethanol, ether
slightly soluble in pyridine
expand Show data source
Very soluble in water and alcohol. Soluble in methanol, acetone, and glycol. Slightly soluble in pyridine expand Show data source
Apperance
-10 Mesh Beads, Ampouled under argon expand Show data source
beads expand Show data source
Crystalline expand Show data source
Crystalline Aggregates expand Show data source
powder expand Show data source
Powder expand Show data source
powder and chunks expand Show data source
Powder, Ampouled under argon expand Show data source
Powder/Granular, Ampouled under argon expand Show data source
White solid
hygroscopic
expand Show data source
Melting Point
162-167°C expand Show data source
550 °C(lit.) expand Show data source
550°C expand Show data source
550°C expand Show data source
552 °C expand Show data source
Boiling Point
1265 °C expand Show data source
1265°C expand Show data source
1265°C expand Show data source
Flash Point
-.4 °F expand Show data source
-18 °C expand Show data source
not flammable expand Show data source
Auto Ignition Point
200°C expand Show data source
Density
0.995 g/mL at 20 °C expand Show data source
1.57 g/mL at 25 °C expand Show data source
3.464 expand Show data source
3.464 g/cm3 expand Show data source
3.464 g/ml expand Show data source
Refractive Index
1.784 expand Show data source
Vapor Pressure
0 expand Show data source
Std enthalpy of formation
-4.044 kJ/g expand Show data source
Storage Condition
Room Temperature (15-30°C), Desiccate expand Show data source
Storage Warning
Hygroscopic expand Show data source
RTECS
OJ5755000 expand Show data source
European Hazard Symbols
Corrosive Corrosive (C) expand Show data source
Flammable Flammable (F) expand Show data source
X expand Show data source
Irritant Irritant (Xi) expand Show data source
Harmful Harmful (Xn) expand Show data source
UN Number
2056 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
Download expand Show data source
German water hazard class
2 expand Show data source
3 expand Show data source
Hazard Class
3 expand Show data source
Packing Group
2 expand Show data source
Risk Statements
11-19-36/37 expand Show data source
22 expand Show data source
22-32-36/37/38 expand Show data source
22-36/38 expand Show data source
R:14/15-34 expand Show data source
Safety Statements
16-26 expand Show data source
26 expand Show data source
26-36 expand Show data source
26-36/37-60 expand Show data source
S:8-45 expand Show data source
TSCA Listed
expand Show data source
EU Index
Not listed expand Show data source
GHS Pictograms
GHS02 expand Show data source
GHS06 expand Show data source
GHS07 expand Show data source
GHS Signal Word
Danger expand Show data source
Warning expand Show data source
NFPA704
NFPA 704 diagram
0
2
0
expand Show data source
GHS Hazard statements
H225-H319-H335 expand Show data source
H301-H315-H319 expand Show data source
H302 expand Show data source
H302-H315-H319 expand Show data source
H302-H315-H319-H335 expand Show data source
GHS Precautionary statements
P210-P261-P305 + P351 + P338 expand Show data source
P261-P305 + P351 + P338 expand Show data source
P280-P301+P310-P305+P351+P338-P302+P352-P405-P501A expand Show data source
P280-P305+P351+P338-P302+P352-P321-P362-P501A expand Show data source
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Faceshields, Gloves expand Show data source
Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter expand Show data source
RID/ADR
UN 2056 3/PG 2 expand Show data source
Supplemental Hazard Statements
Contact with acids liberates very toxic gas. expand Show data source
May form explosive peroxides. expand Show data source
Purity
≥98.0% (dried material, AT) expand Show data source
≥99% expand Show data source
≥99.0% expand Show data source
≥99.0% (dried material, AT) expand Show data source
≥99.9% expand Show data source
≥99.9% trace metals basis expand Show data source
≥99.995% trace metals basis expand Show data source
99% min expand Show data source
99.9% (metals basis) expand Show data source
99.99% (metals basis) expand Show data source
99.995% (metals basis) expand Show data source
99.998% (metals basis) expand Show data source
99.999% trace metals basis expand Show data source
Concentration
1.5 M in THF expand Show data source
54 wt. % in H2O expand Show data source
Grade
anhydrous expand Show data source
puriss. expand Show data source
puriss. p.a. expand Show data source
purum p.a. expand Show data source
ReagentPlus® expand Show data source
Particle Size
-10 mesh expand Show data source
Compostion
LiBr, 68.5 wt. % expand Show data source
LiCl, 22 wt. % expand Show data source
LiF, 9.5 wt. % expand Show data source
Certificate of Analysis
Download expand Show data source
Cation Traces
Ba: ≤10 mg/kg expand Show data source
Ca: ≤10 mg/kg expand Show data source
Ca: ≤100 mg/kg expand Show data source
Ca: ≤50 mg/kg expand Show data source
Cd: ≤5 mg/kg expand Show data source
Cd: ≤50 mg/kg expand Show data source
Co: ≤5 mg/kg expand Show data source
Co: ≤50 mg/kg expand Show data source
Cr: ≤5 mg/kg expand Show data source
Cu: ≤5 mg/kg expand Show data source
Cu: ≤50 mg/kg expand Show data source
Fe: ≤10 mg/kg expand Show data source
Fe: ≤5 mg/kg expand Show data source
Fe: ≤50 mg/kg expand Show data source
K: ≤100 mg/kg expand Show data source
K: ≤50 mg/kg expand Show data source
K: ≤500 mg/kg expand Show data source
Mg: ≤20 mg/kg expand Show data source
Mg: ≤5 mg/kg expand Show data source
Mn: ≤5 mg/kg expand Show data source
Na: ≤300 mg/kg expand Show data source
Na: ≤50 mg/kg expand Show data source
Na: ≤500 mg/kg expand Show data source
Ni: ≤5 mg/kg expand Show data source
Ni: ≤50 mg/kg expand Show data source
Pb: ≤5 mg/kg expand Show data source
Pb: ≤50 mg/kg expand Show data source
Zn: ≤5 mg/kg expand Show data source
Zn: ≤50 mg/kg expand Show data source
Antion Traces
chloride (Cl-): ≤1000 mg/kg expand Show data source
chloride (Cl-): ≤500 mg/kg expand Show data source
sulfate (SO42-): ≤100 mg/kg expand Show data source
sulfate (SO42-): ≤200 mg/kg expand Show data source
sulfate (SO42-): ≤50 mg/kg expand Show data source
Loss on Drying
≤0.5% loss on drying, 400 °C expand Show data source
≤2% loss on drying, 400 °C expand Show data source
Linear Formula
LiBr expand Show data source

DETAILS

DETAILS

MP Biomedicals MP Biomedicals Wikipedia Wikipedia Sigma Aldrich Sigma Aldrich
Sigma Aldrich - 678139 external link
Packaging
100 mL in Sure/Seal™
Sigma Aldrich - 483982 external link
Packaging
5, 25 g in ampule
Sigma Aldrich - 449873 external link
Packaging
25, 100 g in ampule
Sigma Aldrich - 229733 external link
Packaging
25, 125 g in poly bottle
Sigma Aldrich - 429465 external link
Packaging
5, 25 g in ampule
Sigma Aldrich - 213225 external link
Packaging
100, 500 g in poly bottle
2 kg in poly bottle
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Sigma Aldrich - 411515 external link
Packaging
1 L in poly bottle

REFERENCES

REFERENCES

From Suppliers Google Scholar IconGoogle Scholar PubMed iconPubMed Google Books IconGoogle Books
  • • For use in dehydrohalogenation reactions, see Lithium carbonate, 13418. For use in the Horner-Wadsworth-Emmons olefination reaction, see Lithium chloride, A10531, and Triethylamine, A12646. Catalyzes the solvent-free Knoevenagel condenastion of active methylene compounds with aldehydes and ketones: J. Chem. Soc., Perkin 1, 959 (1996). Chemoselective catalyst for the dithioacetalization of aromatic and ɑ?-unsaturated aldehydes under neutral conditions: Synthesis, 58 (1999). Efficient catalyst for the ring-opening of epoxides by amines at room temperature: Eur. J. Org. Chem., 3597 (2004). For a brief feature on uses in synthesis, see: Synlett, 1197 (2005).
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PATENTS

PATENTS

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INTERNET

INTERNET

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