Triphenyltin hydride

• Catalog No.: L00163
• CAS Number: 892-20-6
• M. F.: C18H15Sn
• M. W.: 350.0127
• Purity: 97%

SYNONYMS

• Title: 三苯基氢化锡
• IUPAC name: triphenylstannane
• IUPAC Traditional name: triphenyltin hydride
• Synonyms: Triphenylstannane

DATABASE IDS

• CAS Number: 892-20-6
• MDL Number: MFCD00003004
• Beilstein Number: 3544353
• EC Number: 212-967-8

PROPERTIES

• Purity: 97%
• Boiling Point: 162-168°C/0.5mm
• Density: 1.374
• Flash Point: >110°C(230°F)
• Melting Point: 26-28°C
• Refractive Index: 1.6370
• GHS Hazard statements: H301-H311-H331-H400-H410
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• GHS Precautionary statements: P280H-P303+P361+P353-P305+P351+P338-P309-P310-P501A
• Risk Statements: 23/24/25-50/53
• RTECS: WH8882000
• Safety Statements: 26-27/28-45-60-61
• Storage Warning: Air & Moisture Sensitive
• TSCA Listed: 否
• Hazard Class: 6.1
• UN Number: UN3146
• Packing Group: III

REFERENCES

• For general reactions of organotin hydrides, see Tri-n-butyltin hydride, A13298.
• Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
• 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
  
• Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):