triphenylstannane

• ChemBase ID: 130027
• Molecular Formular: C18H15Sn
• Molecular Mass: 350.0127
• Monoisotopic Mass: 351.01956948
• SMILES: [Sn](c1ccccc1)(c1ccccc1)c1ccccc1
• Canonical SMILES: c1ccc(cc1)[Sn](c1ccccc1)c1ccccc1
• InChI: InChI=1S/3C6H5.Sn/c3*1-2-4-6-5-3-1;/h3*1-5H
• InChIKey: SBXWFLISHPUINY-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: triphenylstannane
• IUPAC Traditional name: triphenyltin; triphenyltin hydride
• Synonyms: Triphenyltin hydride; Triphenyltin hydride; Triphenylstannane; 三苯基锡化氢; 三苯基氢化锡

Database IDs

• CAS Number: 892-20-6
• EC Number: 212-967-8
• MDL Number: MFCD00003004
• Beilstein Number: 3544353
• PubChem SID: 162224312; 24854702
• PubChem CID: 6460; 5357402
• CHEBI ID: 30537
• Chemspider ID: 6217
• Wikipedia Title: Triphenyltin_hydride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.9806
• LogD (pH = 7.4): 3.9806
• Log P: 3.9806
• Molar Refractivity: 77.2229 cm^3
• Polarizability: 34.806534 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 3
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Solubility: insoluble in water; soluble in benzene, THF
• Apperance: colorless
• Melting Point: 26-28°C; 28 °C; 28 °C(lit.)
• Boiling Point: 156 °C (0.15 mm Hg); 162-168°C/0.5mm; 163-165 °C/0.3 mmHg(lit.)
• Flash Point: >110°C(230°F); >230 °F; 113 °C; 235.4 °F
• Density: 1.374; 1.374 g/cm^3; 1.374 g/mL at 25 °C(lit.)
• Refractive Index: 1.6370; n20/D 1.632(lit.)

Safety Information

• Storage Warning: Air & Moisture Sensitive
• RTECS: WH8882000
• European Hazard Symbols: Nature polluting (N); Toxic (T)
• UN Number: 3077; UN3146
• German water hazard class: 3
• Hazard Class: 6.1; 9
• Packing Group: 3; III
• Risk Statements: 23/24/25-50/53; R23/24/25 R50/53
• Safety Statements: 26-27/28-45-60-61; 26-27-28-45-60-61; S26 S27 S28 S45 S60 S61
• TSCA Listed: 否
• GHS Pictograms: GHS06; GHS09
• GHS Signal Word: Danger
• Main Hazard: toxic
• GHS Hazard statements: H301-H311-H331-H400-H410; H301-H311-H331-H410
• GHS Precautionary statements: P261-P273-P280-P301 + P310-P311-P501; P280H-P303+P361+P353-P305+P351+P338-P309-P310-P501A
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
• RID/ADR: UN 3077 9/PG 3
• Storage Temperature: 2-8°C

Product Information

• Purity: 97%
• Linear Formula: (C6H5)3SnH

DETAILS

Sigma Aldrich - 244775

Packaging
5, 25 g in glass bottle

REFERENCES

• For general reactions of organotin hydrides, see Tri-n-butyltin hydride, A13298.
• Reagent for free-radical desulfurization of the thionocarbonates of 1,2-diols to the corresponding methylenedioxy compounds: J. Org. Chem., 62, 1690 (1997).
• 2-(Bromomethyl)penicillin V methyl ester undergoes ring-expansion via the methylene radical, to give the corresponding cepham: Tetrahedron, 44, 5953 (1988):
  
• Hydrostannylation of terminal alkynes is conveniently carried out in the presence of triethylboron. Reaction is faster than with tributyl tin hydride and gives higher yields. Stereoselectivity varies from 69-100% (E): Tetrahedron, 45, 923 (1989):