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Chlorodiphenylphosphine

Catalog No. A14241 Name Alfa Aesar
CAS Number 1079-66-9 Website
M. F. C12H10ClP Telephone
M. W. 220.634561 Fax
Purity 97% Email
Storage Chembase ID: 79354

SYNONYMS

Title
二苯基氯化膦
IUPAC name
chlorodiphenylphosphane
IUPAC Traditional name
chlorodiphenylphosphine
Synonyms
Diphenyl chlorophosphine
Diphenylphosphinous chloride

DATABASE IDS

MDL Number MFCD00000529
CAS Number 1079-66-9
EC Number 214-093-2
Beilstein Number 512032

PROPERTIES

Purity 97%
Boiling Point 318-321°C
Density 1.204
Flash Point 138°C(280°F)
Melting Point 14-16°C
Refractive Index 1.6350
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Hazard statements H301-H314-H318
European Hazard Symbols X
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P280-P303+P361+P353-P305+P351+P338-P310-P402
Risk Statements 14-22-34
Safety Statements 26-36/37/39-45
Storage Warning Air & Moisture Sensitive
TSCA Listed
Hazard Class 8
UN Number UN3265
Packing Group II

DETAILS

REFERENCES

  • Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).