Home > Compound List > Compound details
1079-66-9 molecular structure
click picture or here to close

chlorodiphenylphosphane

ChemBase ID: 79354
Molecular Formular: C12H10ClP
Molecular Mass: 220.634561
Monoisotopic Mass: 220.02086463
SMILES and InChIs

SMILES:
P(c1ccccc1)(c1ccccc1)Cl
Canonical SMILES:
ClP(c1ccccc1)c1ccccc1
InChI:
InChI=1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
InChIKey:
XGRJZXREYAXTGV-UHFFFAOYSA-N

Cite this record

CBID:79354 http://www.chembase.cn/molecule-79354.html

Collapse All Expand All

NAMES AND DATABASE IDS

NAMES AND DATABASE IDS

Names Database IDs
IUPAC name
chlorodiphenylphosphane
IUPAC Traditional name
chlorodiphenylphosphine
Synonyms
Diphenylphosphinous chloride
Chlorodiphenylphosphine
P-Chlorodiphenylphosphine
ClPPh2
PPh2Cl
Chlorodiphenylphosphine
Diphenyl chlorophosphine
CHLORODIPHENYLPHOSPINE
chlorodiphenylphosphine
p-chlorodiphenylphosphine
diphenyl phosphine chloride
diphenylchlorophosphine
P-氯代二苯基膦
P-氯代二苯基膦
二苯基氯化膦
氯代二苯基膦
二苯基氯化膦
CAS Number
1079-66-9
EC Number
214-093-2
MDL Number
MFCD00000529
Beilstein Number
512032
PubChem SID
24854711
162044117
24892660
PubChem CID
66180
Chemspider ID
59567
Wikipedia Title
Chlorodiphenylphosphine

CALCULATED PROPERTIES

CALCULATED PROPERTIES

JChem
H Acceptors H Donor
LogD (pH = 5.5) 4.1389  LogD (pH = 7.4) 4.1389 
Log P 4.1389  Molar Refractivity 62.2849 cm3
Polarizability 24.455183 Å3 Polar Surface Area 0.0 Å2
Rotatable Bonds Lipinski's Rule of Five true 

PROPERTIES

PROPERTIES

Physical Property Safety Information Product Information Bioassay(PubChem)
Solubility
Reacts in water expand Show data source
Apperance
clear to light yellow liquid expand Show data source
Liquid expand Show data source
Melting Point
14-16°C expand Show data source
Boiling Point
318-321°C expand Show data source
320 ?C expand Show data source
320 °C(lit.) expand Show data source
320°C expand Show data source
Flash Point
112 °C expand Show data source
112°C expand Show data source
138°C(280°F) expand Show data source
233.6 °F expand Show data source
Density
1.194 g/mL at 25 °C expand Show data source
1.204 expand Show data source
1.229 expand Show data source
1.229 g cm-3 expand Show data source
1.229 g/mL at 25 °C(lit.) expand Show data source
Refractive Index
1.6350 expand Show data source
1.636 expand Show data source
1.6360 expand Show data source
n20/D 1.636(lit.) expand Show data source
Vapor Density
7.8 (vs air) expand Show data source
Storage Warning
Air & Moisture Sensitive expand Show data source
Corrosive/Harmful/Lachrymatory/Air Sensitive/Moisture Sensitive/Store under Argon expand Show data source
European Hazard Symbols
Corrosive Corrosive (C) expand Show data source
X expand Show data source
UN Number
3265 expand Show data source
UN3265 expand Show data source
MSDS Link
Download expand Show data source
Download expand Show data source
Download expand Show data source
German water hazard class
2 expand Show data source
Hazard Class
8 expand Show data source
Packing Group
2 expand Show data source
II expand Show data source
Risk Statements
14-22-34 expand Show data source
14-34 expand Show data source
R:34-36/37/38 expand Show data source
Safety Statements
26-36/37/39-45 expand Show data source
S:26-27/28-36/37/39-46-64 expand Show data source
TSCA Listed
expand Show data source
GHS Pictograms
GHS05 expand Show data source
GHS06 expand Show data source
GHS Signal Word
Danger expand Show data source
GHS Hazard statements
H301-H314-H318 expand Show data source
H314 expand Show data source
H314-H318 expand Show data source
GHS Precautionary statements
P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A expand Show data source
P280-P303+P361+P353-P305+P351+P338-P310-P402 expand Show data source
P280-P305 + P351 + P338-P310 expand Show data source
Personal Protective Equipment
Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter expand Show data source
RID/ADR
UN 3265 8/PG 2 expand Show data source
Supplemental Hazard Statements
Reacts violently with water. expand Show data source
Purity
≥95.0% (GC) expand Show data source
96% expand Show data source
97% expand Show data source
98+% expand Show data source
Grade
purum expand Show data source
Certificate of Analysis
Download expand Show data source
Linear Formula
(C6H5)2PCl expand Show data source

DETAILS

DETAILS

MP Biomedicals MP Biomedicals Wikipedia Wikipedia Sigma Aldrich Sigma Aldrich
MP Biomedicals - 05213832 external link
MP Biomedicals Rare Chemical collection
Sigma Aldrich - C39601 external link
Application
Precursors used in the synthesis of various phosphines.
Used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation.
Packaging
25, 100, 500 g in glass bottle
Sigma Aldrich - 24485 external link
Caution
may become turbid on storage

REFERENCES

REFERENCES

From Suppliers Google Scholar IconGoogle Scholar PubMed iconPubMed Google Books IconGoogle Books
  • • Reacts with Li metal in liquid ammonia to give the Li diphenylphosphide: Tetrahedron Lett., 21, 3535 (1980). Reaction with vinyl lithium intermediates from the reaction of alkyllithiums with sulfonylhydrazones (see p-Toluenesulfonyl hydrazide, A13529) gives vinylphosphines: Tetrahedron Lett., 22, 4619 (1981).
  • Searching...Please wait...

PATENTS

PATENTS

PubChem iconPubChem Patent Google Patent Search IconGoogle Patent

INTERNET

INTERNET

Baidu iconBaidu google iconGoogle