Acetone

• Catalog No.: L10407
• CAS Number: 67-64-1
• M. F.: C3H6O
• M. W.: 58.07914
• Purity: 99+%

SYNONYMS

• Title: 丙酮
• IUPAC name: propan-2-one
• IUPAC Traditional name: acetone

DATABASE IDS

• EC Number: 200-662-2
• MDL Number: MFCD00008765
• CAS Number: 67-64-1
• Beilstein Number: 635680
• Merck Index: 1466

PROPERTIES

• Purity: 99+%
• Boiling Point: 56°C
• Density: 0.791
• Flash Point: -17°C(1°F)
• Melting Point: -94°C
• Refractive Index: 1.3590
• GHS Hazard statements: H225-H319-H336
• European Hazard Symbols: Irritant (Xi)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-36-66-67
• RTECS: AL3150000
• Safety Statements: 9-16-26-46
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1090
• Packing Group: II

REFERENCES

• Precursor of dimethyldioxirane, by reaction with K monopersulfate, and isolation in solution by low temperature distillation. For details, see: Chem. Ber., 124, 2377 (1991). It is an excellent reagent for rapid, stereospecific epoxidation of alkenes under mild conditions: J. Org. Chem., 50, 2847 (1985); Org. Synth. Coll., 9, 288 (1998). For improved work-up procedure allowing the possibility of more concentrated solutions or the isolation of acetone-free material, see: Tetrahedron Lett., 37, 3585 (1996). For biphasic, environmentally-friendly system (EtOAc-H₂ O), see: Org. Process Res. Dev., 6, 407 (2002). Selective oxidation of phosphorus ylides occurs under mild conditions, providing a route to vicinal tricarbonyl derivatives: J. Org. Chem., 60, 8231 (1995). For conversion of ɑ-bromo-?-dicarbonyls to vicinal tricarbonyls, see: Tetrahedron Lett., 36, 7735 (1995). For formation of singlet oxygen by deoxygenation of heteroaromatic N-oxides, e.g. 4-diethylaminopyridine N-oxide, see: J. Chem. Soc., Chem.Commun., 1831 (1995). For reviews of dioxiranes, see: Acc. Chem. Res., 22, 205 (1989); Chem. Rev., 89, 1187 (1989).