Ethyldiphenylphosphine

• Catalog No.: 03460
• CAS Number: 607-01-2
• M. F.: C14H15P
• M. W.: 214.242661
• Purity: ≥97.0% (GC)

SYNONYMS

• Title: 乙基二苯基膦
• IUPAC name: ethyldiphenylphosphane
• IUPAC Traditional name: phosphine, ethyldiphenyl-
• Synonyms: 乙二苯膦; Diphenylethylphosphine; NSC 151254

DATABASE IDS

• Beilstein Number: 744253
• PubChem SID: 24845482
• MDL Number: MFCD00015170
• CAS Number: 607-01-2

PROPERTIES

• Grade: purum
• Linear Formula: (C6H5)2PCH2CH3
• Purity: ≥97.0% (GC)
• Boiling Point: 293 °C(lit.)
• Density: 1.048 g/mL at 25 °C(lit.)
• Flash Point: 110 °C
• Flash Point: 230 °F
• Refractive Index: n20/D 1.614(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H315-H319-H335
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 22-36/37/38
• RTECS: SY9242500
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Other Notes
Ligand used in organometallic chemistry10,11,12,13
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9

Description (简体中文)

Other Notes
用于有机金属化学的配体10,11,12,13
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9