ethyldiphenylphosphane

• ChemBase ID: 112257
• Molecular Formular: C14H15P
• Molecular Mass: 214.242661
• Monoisotopic Mass: 214.09113711
• SMILES: CCP(c1ccccc1)c1ccccc1
• Canonical SMILES: CCP(c1ccccc1)c1ccccc1
• InChI: InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
• InChIKey: WUOIAOOSKMHJOV-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: ethyldiphenylphosphane
• IUPAC Traditional name: phosphine, ethyldiphenyl-
• Synonyms: DIPHENYL ETHYL PHOSPHINE; NSC 151254; Diphenylethylphosphine; Ethyldiphenylphosphine; 乙二苯膦; 乙基二苯基膦

Database IDs

• CAS Number: 607-01-2
• MDL Number: MFCD00015170
• Beilstein Number: 744253
• PubChem SID: 24845482; 24860439; 162097391
• PubChem CID: 69082

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 3.9824
• LogD (pH = 7.4): 3.9824
• Log P: 3.9824
• Molar Refractivity: 66.4955 cm^3
• Polarizability: 26.402058 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 3
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 130°C; 130-132°C/1mm; 293 °C(lit.)
• Flash Point: 110 °C; 230 °F
• Density: 1.048; 1.048 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.614(lit.)

Safety Information

• Storage Warning: Air Sensitive
• RTECS: SY9242500
• European Hazard Symbols: X; Harmful (Xn)
• UN Number: UN3278
• German water hazard class: 3
• Hazard Class: 6.1
• Packing Group: III
• Risk Statements: 22-36/37/38
• Safety Statements: 26-36; 26-36/37
• TSCA Listed: 否
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338; P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Product Information

• Purity: ≥97.0% (GC); 98%
• Grade: purum
• Linear Formula: (C6H5)2PCH2CH3

DETAILS

MP Biomedicals - 05223180

MP Biomedicals Rare Chemical collection

Sigma Aldrich - 336904

Packaging
2 g in glass bottle
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9

Sigma Aldrich - 03460

Other Notes
Ligand used in organometallic chemistry10,11,12,13
Application
Catalyst for:
• Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide1
• Regio- and stereoselective hydroalkynylation of methylenecyclopropanes2
• Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles3
• Dimer to monomer conversion4
• Tandem Morita-Baylis-Hillman/Michael addition reactions5
• Platinum-catalyzed cyclization6
• Regioselective and stereoselective [3+2] cycloaddition7
• Platinum-catalyzed intermolecular hydroamination8
• Hydroformylation reactions9