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Potassium bis(trimethylsilyl)amide_Molecular_structure_CAS_40949-94-8)
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Potassium bis(trimethylsilyl)amide

Catalog No. 324671 Name Sigma Aldrich
CAS Number 40949-94-8 Website http://www.sigmaaldrich.com
M. F. C6H18KNSi2 Telephone 1-800-521-8956
M. W. 199.48312 Fax
Purity 95% Email
Storage Chembase ID: 129053

SYNONYMS

Title
双(三甲基硅烷基)氨基钾
IUPAC name
potassiobis(trimethylsilyl)amine
IUPAC Traditional name
potassiobis(trimethylsilyl)amine
Synonyms
六甲基二硅基胺基钾
六甲基二硅氮烷 钾盐
Potassium hexamethyldisilazide
Hexamethyldisilazane potassium salt

DATABASE IDS

Beilstein Number 4006754
CAS Number 40949-94-8
PubChem SID 24859460
MDL Number MFCD00010330

PROPERTIES

Linear Formula [(CH3)3Si]2NK
Purity 95%
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3263 8/PG 3
Risk Statements 14-34
Safety Statements 26-36/37/39-43-45
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 8
UN Number 3263
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Packaging
5, 25, 100 g in glass bottle
Application
Anionic initiator used in the preparation of poly(ethylene oxide).1 Sterically hindered base employed in selective cyclization reactions.2 Also used in the preparation of lanthanide complexes.3,4
Description (简体中文)
包装
5, 25, 100 g in glass bottle
Application
阴离子引发剂,用于制备聚环氧乙烷。1具有空间位阻的碱,用于选择性环化反应。2还可用于制备镧系配合物。3,4

REFERENCES