Palladium hydroxide on carbon

• Catalog No.: 212911
• CAS Number: 12135-22-7
• M. F.: H2O2Pd
• M. W.: 140.43468

SYNONYMS

• Title: 碳负载氢氧化钯
• IUPAC name: palladiumdiol
• IUPAC Traditional name: palladiumdiol
• Synonyms: Pearlman’s catalyst; Pd(OH)2/C; Pearlman 催化剂

DATABASE IDS

• EC Number: 235-219-2
• CAS Number: 12135-22-7
• PubChem SID: 24852754
• MDL Number: MFCD00064599

PROPERTIES

• Contains: ≤50% water
• Empirical Formula (Hill Notation): H2O2Pd
• Extent of Labeling: 20 wt. % loading (dry basis)
• Matrix: carbon, wet support
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation.1
Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.
Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.
Packaging
1, 10, 50, 500 g in glass bottle

Description (简体中文)

Application
Pd/C 和 Pd(OH)2/C 的加成反应可提高 N- 或 O-脱苄基反应的效率。1
在分子内和分子间过程中高效催化芳基碘和芳基溴的直接芳基化反应。
对苄基-氮键的氢解反应特别有效，并且已证明即使对于其他碳负载钯催化剂失效的情况也同样有效。
包装
1, 10, 50, 500 g in glass bottle