palladiumdiol

• ChemBase ID: 146067
• Molecular Formular: H2O2Pd
• Molecular Mass: 140.43468
• Monoisotopic Mass: 139.9089653
• SMILES: O[Pd]O
• Canonical SMILES: O[Pd]O
• InChI: InChI=1S/2H2O.Pd/h2*1H2;/q;;+2/p-2
• InChIKey: NXJCBFBQEVOTOW-UHFFFAOYSA-L

NAMES AND DATABASE IDS

Names

• IUPAC name: palladiumdiol
• IUPAC Traditional name: palladiumdiol
• Synonyms: Pd(OH)2/C; Pearlman’s catalyst; Palladium hydroxide on carbon; Pearlman’s catalysts; Palladium hydroxide on activated charcoal; Pearlman 催化剂; 碳负载氢氧化钯; 活性炭负载氢氧化钯

Database IDs

• CAS Number: 12135-22-7
• EC Number: 235-219-2
• MDL Number: MFCD00064599
• PubChem SID: 162240266; 24886931; 24859831; 24852754
• PubChem CID: 82930

CALCULATED PROPERTIES

• Acid pKa: 16.271217
• H Acceptors: 2
• H Donor: 2
• LogD (pH = 5.5): -1.0724
• LogD (pH = 7.4): -1.0724
• Log P: -1.0724
• Molar Refractivity: 5.1292 cm^3
• Polarizability: 7.1674 Å^3
• Polar Surface Area: 40.46 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true

PROPERTIES

Safety Information

• European Hazard Symbols: Irritant (Xi)
• German water hazard class: 3
• Risk Statements: 36/37/38
• Safety Statements: 26
• GHS Pictograms: GHS07
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• GHS Precautionary statements: P261-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves; Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Product Information

• Purity: 10-20% Pd basis (based on dry substance)
• Contains: ~50% water; ~50% water as stabilizer; ≤50% water
• Extent of Labeling: 20 wt. % loading (dry basis)
• Matrix: carbon, wet support
• Quality: moistened with water
• Weight: Unit weight excludes weight of water
• Empirical Formula (Hill Notation): H2O2Pd

DETAILS

Sigma Aldrich - 76063

Application
Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.
Hydrogenation catalyst
Packaging
5, 50 g in glass bottle

Sigma Aldrich - 330094

Application
Catalyst for hydrogenolysis of benzyl groups and epoxides; used to reduce nitro compounds to amines and as dehydrogenation reagent.
Useful reagent for debenzylation.
Packaging
10, 50 g in glass bottle

Sigma Aldrich - 212911

Application
Addition of Pd/C to Pd(OH)2/C improves the efficiency of N- or O-debenzylation.1
Effectively catalyzes the direct arylation reactions of aryl iodides and bromides in both intra- and intermolecular processes.
Particularly active for hydrogenolysis of benzyl-nitrogen bonds, and has proven successful even where other palladium-on-carbon catalysts have failed.
Packaging
1, 10, 50, 500 g in glass bottle