(aminomethyl)trimethylsilane

• ChemBase ID: 124697
• Molecular Formular: C4H13NSi
• Molecular Mass: 103.23822
• Monoisotopic Mass: 103.08172595
• SMILES: [Si](CN)(C)(C)C
• Canonical SMILES: NC[Si](C)(C)C
• InChI: InChI=1S/C4H13NSi/c1-6(2,3)4-5/h4-5H2,1-3H3
• InChIKey: YVWPNDBYAAEZBF-UHFFFAOYSA-N

NAMES AND DATABASE IDS

Names

• IUPAC name: (aminomethyl)trimethylsilane
• IUPAC Traditional name: (aminomethyl)trimethylsilane
• Synonyms: (Aminomethyl)trimethylsilane; (Trimethylsilyl)methylamine; (trimethylsilyl)methanamine; 氨甲基三甲基硅烷; (三甲基硅基)甲胺

Database IDs

• CAS Number: 18166-02-4
• EC Number: 242-049-2
• MDL Number: MFCD00042931
• Beilstein Number: 1731488
• PubChem SID: 162219050; 24889722
• PubChem CID: 87488

CALCULATED PROPERTIES

• H Acceptors: 1
• H Donor: 1
• LogD (pH = 5.5): -1.8655124
• LogD (pH = 7.4): -1.2633641
• Log P: 1.5628
• Molar Refractivity: 25.2901 cm^3
• Polarizability: 12.561891 Å^3
• Polar Surface Area: 26.02 Å^2
• Rotatable Bonds: 1
• Lipinski's Rule of Five: true

PROPERTIES

Physical Property

• Boiling Point: 92-94 °C(lit.)
• Flash Point: 48.2 °F; 9 °C
• Density: 0.771 g/mL at 20 °C(lit.)
• Refractive Index: n20/D 1.416

Safety Information

• European Hazard Symbols: Corrosive (C); Flammable (F)
• UN Number: 2733
• German water hazard class: 3
• Hazard Class: 3
• Packing Group: 2
• Risk Statements: 11-34-37
• Safety Statements: 16-26-36/37/39-45
• GHS Pictograms: GHS02; GHS05
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H314
• GHS Precautionary statements: P210-P280-P305 + P351 + P338-P310
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• RID/ADR: UN 2733 3/PG 2

Product Information

• Purity: ≥98.0% (GC)
• Empirical Formula (Hill Notation): C4H13NSi

DETAILS

Sigma Aldrich - 92768

Other Notes
Synthesis of trimethylsilyl-diazomethane1; 1,3-Cycloaddition of its imine2; preparation of azomethine ylides from ketones3
Packaging
5, 25 mL in glass bottle