lithium(1+) ion chloride

• ChemBase ID: 102979
• Molecular Formular: ClLi
• Molecular Mass: 42.394
• Monoisotopic Mass: 41.98485723
• SMILES: [Li+].[Cl-]
• Canonical SMILES: [Li+].[Cl-]
• InChI: InChI=1S/ClH.Li/h1H;/q;+1/p-1
• InChIKey: KWGKDLIKAYFUFQ-UHFFFAOYSA-M

NAMES AND DATABASE IDS

Names

• IUPAC name: lithium(1+) ion chloride
• IUPAC Systematic name: Lithium(1+) chloride
• IUPAC Traditional name: LithoTab chloride; lithium(1+) ion chloride
• Synonyms: Additive Screening Solution 15/Fluka kit no 78374; Lithium chloride solution; Lithium chloride 1 M solution; Lithium ion standard solution; Chlorku litu; Chlorure de lithium; Lithiumchlorid; LITHIUM CHLORIDE ANHYDROUS; LITHIUM CHLORIDE, ANHYDROUS; Lithium chloride, anhydrous; Lithium chloride hydrate, Puratronic®; Lithium chloride, ACS; Lithium chloride, ultra dry; LITHIUM CHLORIDE; LITHIUM CHLORIDE, ACS; Lithium chloride; Lithium chloride solution; Lithium standard solution; Lithium atomic spectroscopy standard concentrate 1.00 g Li; 氯化锂 溶液; 锂离子标准溶液; 无水氯化锂; 氯化锂水合物, Puratronic®; 氯化锂, ACS; 氯化锂,超干; 氯化锂, 超干; 氯化锂; 氯化锂 溶液; Lithium standard solution; 锂原子光谱分析标准浓缩液 1.00g Li

Database IDs

• CAS Number: 7447-41-8; 85144-11-2
• EC Number: 231-212-3; 231-791-2
• MDL Number: MFCD00011078; MFCD00149764
• Merck Index: 145528
• PubChem SID: 24866862; 24882224; 24884921; 24882223; 24868517; 24896459; 24278056; 24886496; 24852187; 24852673; 24858795; 24896448; 24845370; 162089362
• PubChem CID: 433294
• CHEBI ID: 48607
• CHEMBL: 69710
• Chemspider ID: 22449
• MeSH Name: Lithium+chloride
• Unique Ingredient Identifier: G4962QA067
• Wikipedia Title: Lithium_chloride

CALCULATED PROPERTIES

• H Acceptors: 0
• H Donor: 0
• LogD (pH = 5.5): 0.0
• LogD (pH = 7.4): 0.0
• Log P: 0.0
• Molar Refractivity: 0.0 cm^3
• Polarizability: 1.7969184 Å^3
• Polar Surface Area: 0.0 Å^2
• Rotatable Bonds: 0
• Lipinski's Rule of Five: true
• Acid pKa: 3.09

PROPERTIES

Physical Property

• Solubility: 55 g/100 mL (20 °C) ; 128.3 g/100 mL (100 °C) in water; acetone: soluble; ethanol: soluble; H2O: soluble; H2O: soluble1 M at 20 °C, clear, colorless; H2O: soluble1 M, clear, colorless; highly soluble in pyridine, nitrobenzene ; 4.1 g/100 mL (acetone) ; 17 g/100 mL (methanol) ; 2.5 g/100 mL (ethanol); pyridine: soluble; Very soluble in water, alcohol, ether, pyridine, and nitrobenzene
• Apperance: -10 Mesh Beads, Ampouled under argon; -20 Mesh; beads; Crystalline Aggregates; Crystalline, Ampouled under argon; Granular; powder; Powder, Ampouled under argon; white solid ; hygroscopic
• Melting Point: >98°C -H{2}O; 605 °C; 605 °C(lit.); 605°C; 605°C
• Boiling Point: 1325-1360°C; 1355°C; 1382 °C (decomp); 1383 °C/1 atm(lit.)
• Flash Point: -20 °C; -4 °F; Non-flammable
• Density: 0.913 g/mL at 25 °C; 1.02 g/mL at 20 °C; 1.093 g/mL at 25 °C; 1.21 g/mL at 20 °C; 1.78; 2.068; 2.068 g/cm^3; 2.1 g/ml
• Refractive Index: 1.662
• Vapor Pressure: 0
• Partition Coefficient: Log P(oct) = -2.66
• Absorption Wavelength: λ: 260 nm Amax: 0.01; λ: 260 nm Amax: 0.02; λ: 260 nm Amax: 0.04; λ: 280 nm Amax: 0.01; λ: 280 nm Amax: 0.02
• Heat Capacity: 1.132 J/(g K)
• Std enthalpy of formation: -9.638 kJ/g
• pH: 5.0-7.0 (25 °C); 5.0-7.5 (25 °C, 1 M in H2O); 5.5-7.5 (25 °C, 50 mg/mL in H2O)

Safety Information

• Storage Condition: Room Temperature (15-30°C), Desiccate
• Storage Warning: Hygroscopic
• RTECS: OJ5450000; OJ5950000
• European Hazard Symbols: Corrosive (C); Flammable (F); X; Irritant (Xi); Harmful (Xn)
• UN Number: 2056
• German water hazard class: 1; 3
• Hazard Class: 3
• Packing Group: 2
• Risk Statements: 11-19-36/37; 21/22-38-41; 22-36/37/38; R:22-34
• Safety Statements: 16-26; 26; 26-36/37; 26-36/37/39; S:27/28-36/37/39-45
• TSCA Listed: 是
• EU Index: Not listed
• GHS Pictograms: GHS02; GHS05; GHS06; GHS07
• GHS Signal Word: Danger; Warning
• NFPA704:
  

  0

  1

  0
• GHS Hazard statements: H225-H319-H335; H301-H315-H319-H335; H302 + H312-H315-H318; H302-H315-H319-H335
• GHS Precautionary statements: P210-P261-P305 + P351 + P338; P261-P301+P310-P305+P351+P338-P302+P352-P405-P501A; P261-P305 + P351 + P338; P280-P305 + P351 + P338
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves; Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter; Eyeshields, Faceshields, Gloves; Eyeshields, Gloves
• RID/ADR: UN 2056 3/PG 2
• Supplemental Hazard Statements: May form explosive peroxides.
• Storage Temperature: 2-8°C

Product Information

• Purity: ≥99%; ≥98%; ≥98.0%; ≥98.0% (AT); ≥99%; ≥99.0%; ≥99.0% (AT); ≥99.0% (titration); ≥99.9% trace metals basis; ≥99.99% trace metals basis; 98+%; 99%; 99% min; 99.65%; 99.9% (metals basis); 99.995% (metals basis); 99.996% (metals basis); 99.998% trace metals basis
• Concentration: ~8 M in H2O; 0.01 M Li; 0.5 M in anhydrous tetrahydrofuran; 1 M in 1,3-dimethyl-2-imidazolidinone; 1 mg/mL Li; 1.00 g/L; 10 M in H2O; 1000 ppm Li; 8 M
• Grade: ACS; ACS reagent; anhydrous; for ion-selective electrodes; for molecular biology; puriss.; puriss. p.a.; purum p.a.; REAGENT; ReagentPlus®; SAJ first grade; SAJ special grade
• Particle Size: -10 mesh
• Suitability: suitable for atomic absorption spectrometry
• Impurities: <0.001% total nitrogen (N); ≤0.0005% Phosphorus (P); ≤0.001% heavy metals (as Pb); ≤0.001% total nitrogen (N); ≤0.005% heavy metals (as Pb); ≤0.008 meq/g Titr. base; ≤0.01% insolubles; ≤0.1% Insoluble matter; ≤50 ppm water; DNases, none detected; insoluble matter, passes filter test; phosphatases, none detected; proteases, none detected; RNases, none detected
• Cation Traces: Al: ≤0.0005%; Al: ≤1 mg/kg; Al: ≤5 mg/kg; As: ≤0.1 mg/kg; Ba: ≤0.0005%; Ba: ≤0.003%; Ba: ≤1 mg/kg; Ba: ≤10 mg/kg; Ba: ≤100 mg/kg; Bi: ≤1 mg/kg; Bi: ≤5 mg/kg; Ca: ≤0.001%; Ca: ≤0.01%; Ca: ≤10 mg/kg; Ca: ≤100 mg/kg; Ca: ≤20 mg/kg; Ca: ≤5 mg/kg; Ca: ≤50 mg/kg; Cd: ≤1 mg/kg; Cd: ≤5 mg/kg; Cd: ≤50 mg/kg; Co: ≤1 mg/kg; Co: ≤5 mg/kg; Co: ≤50 mg/kg; Cr: ≤1 mg/kg; Cr: ≤5 mg/kg; Cu: ≤0.0005%; Cu: ≤1 mg/kg; Cu: ≤5 mg/kg; Cu: ≤50 mg/kg; Fe: ≤0.001%; Fe: ≤0.002%; Fe: ≤1 mg/kg; Fe: ≤10 mg/kg; Fe: ≤5 mg/kg; Fe: ≤50 mg/kg; heavy metals (as Pb): ≤0.002%; K: ≤0.005%; K: ≤0.01%; K: ≤100 mg/kg; K: ≤20 mg/kg; K: ≤2000 mg/kg; K: ≤50 mg/kg; Mg: ≤0.0005%; Mg: ≤1 mg/kg; Mg: ≤20 mg/kg; Mg: ≤5 mg/kg; Mn: ≤1 mg/kg; Mn: ≤5 mg/kg; Mo: ≤1 mg/kg; Mo: ≤5 mg/kg; Na: ≤0.005%; Na: ≤0.20%; Na: ≤10 mg/kg; Na: ≤20 mg/kg; Na: ≤200 mg/kg; Na: ≤3000 mg/kg; Na: ≤50 mg/kg; NH4+: ≤0.1%; Ni: ≤1 mg/kg; Ni: ≤10 mg/kg; Ni: ≤50 mg/kg; Pb: ≤0.001%; Pb: ≤1 mg/kg; Pb: ≤5 mg/kg; Pb: ≤50 mg/kg; Sr: ≤1 mg/kg; Sr: ≤5 mg/kg; Zn: ≤0.0005%; Zn: ≤1 mg/kg; Zn: ≤5 mg/kg; Zn: ≤50 mg/kg
• Antion Traces: nitrate (NO3-): ≤0.001%; nitrate (NO3-): ≤10 mg/kg; sulfate (SO42-): ≤0.01%; sulfate (SO42-): ≤100 mg/kg; sulfate (SO42-): ≤50 mg/kg
• Foreign Activity: DNase, NICKase, RNase, protease, none detected; DNase, RNase, protease, none detected
• Shelf Life: (limited shelf life, expiry date on the label)
• Loss on Drying: <1% loss on drying, 110°C; ≤1% loss on drying, 110 °C; ≤1.0% loss on drying; ≤2% loss on drying, 110 °C
• Quality: ampule
• λ: 1 M in H2O; neat
• Product Line: BioUltra
• Linear Formula: LiCl

DETAILS

MP Biomedicals - 02152538

ACS Reagent Grade
Purity: ≥99%

MP Biomedicals - 02150134

Crystalline

MP Biomedicals - 02194010

Molecular Biology Reagent
Purity: >99%

Sigma Aldrich - L7026

Application
可用于选择性地沉淀 RNA。
Preparation Note
用 18 兆欧水制备 经 0.2μm 过滤器过滤

Sigma Aldrich - 62476

Other Notes
Precipitation of RNA1,2,3; Transformation of intact yeast cells treated with alkali cations4

Sigma Aldrich - L9650

Application
可用于选择性地沉淀 RNA。

Sigma Aldrich - 667544

Packaging
100 mL in Sure/Seal™

Sigma Aldrich - 694576

Packaging
50 mL in glass bottle

Sigma Aldrich - 429457

Packaging
5, 25 g in ampule
Application
Used in formation of an active Mn(0) species useful for radical cyclization reactions.1

Sigma Aldrich - 449881

Packaging
10, 50 g in ampule
Application
Used in formation of an active Mn(0) species useful for radical cyclization reactions.1

Sigma Aldrich - 203637

Packaging
10, 50, 100 g in poly bottle

Sigma Aldrich - 62378

General description
Visit our Sensor Applications portal to learn more.
Preparation Note
prepared with LiCl and H2O

Sigma Aldrich - 213233

Packaging
100, 500 g in poly bottle
12 kg in poly drum
2 kg in poly bottle
Legal Information
ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC

Sigma Aldrich - 02685

Preparation Note
prepared with LiCl and H2O

Sigma Aldrich - 62477

Other Notes
Potent inhibitor of the phosphatase that cleaves inositol-1-phosphate to inositol1; For the construction of the Li+-selective electrode for studies on the melibiose carrier of E. coli2; Exposure to Li+ (LiCl) gives rise to dorso-anterior development in Xenopus laevis embryos3; Constituent of certain culture media for the inhibition of gram negative bacteria e.g. Enrichment Broth acc. to Giolitti and Cantoni, Staph. Enrichment Broth Base, Vogel-Johnson Agar Base etc.

Sigma Aldrich - 310468

Packaging
100, 500 g in poly bottle
2.5 kg in poly bottle
5 g in glass bottle

REFERENCES

• In DMF, acts as a base in dehydrohalogenation reactions; see, for example: Org. Synth. Coll., 4, 162 (1963). See also lithium carbonate (preceding entry). A comparison has been made of its activity with or without microwave irradiation for promoting the Knoevenagel condensation in N-methylpyrrolidinone, e.g. of malononitrile: Chem. Commun., 773 (1998).
• For use in the dealkylation of activated aralkyl ethers, see: Synthesis, 287 (1989).
• In the Wadsworth-Emmons olefination reaction, Triethylamine, A12646, was effective as base in combination a number of metal salts of which Li halides gave the highest yields: J. Org. Chem., 50, 2624 (1985).
• Additive in the Stille coupling reaction of alkyl and arylstannanes with aryl triflates, preventing decomposition of the palladium complex catalyst: J. Am. Chem. Soc., 106, 4630 (1984); 108, 3033 (1986); see also Tri-n-butyltin chloride, A10746.
• The combination of LiCl and water in DMSO provides a mild and efficient method for deprotection of THP ethers: J. Org. Chem., 61, 6038 (1996), and ethylene acetals: Tetrahedron Lett., 38, 7271 (1997).