Oxone®, monopersulfate

• Catalog No.: 89892
• CAS Number: 70693-62-8
• M. F.: H3K5O18S4
• M. W.: 614.76452

SYNONYMS

• Title: Oxone®, 单过硫酸 (过硫酸钾)
• IUPAC name: pentapotassium bis(O-sulfonoperoxoatooxidanol) hydrogen sulfate sulfate
• IUPAC Traditional name: pentapotassium bis(sulfodioxidanide) hydrogensulfate sulfate
• Synonyms: Potassium peroxymonosulfate; Potassium monopersulfate triple salt

DATABASE IDS

• MDL Number: MFCD00040551
• EC Number: 274-778-7
• CAS Number: 70693-62-8

PROPERTIES

• Apperance: Granular
• Density: 1.15
• GHS Hazard statements: H272-H301-H317-H334-H314-H318
• European Hazard Symbols: X
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Oxidising (O)
• GHS Precautionary statements: P221-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 8-22-34-42/43
• Safety Statements: 17-22-26-36/37/39-45
• Storage Warning: Hygroscopic
• TSCA Listed: 是
• Hazard Class: 8
• UN Number: UN3084
• Packing Group: II

REFERENCES

• Versatile oxidizing agent. For use in the generation of dioxiranes. Primary arylamines in aqueous acetone buffered with bicarbonate give nitro compounds in good yield: Tetrahedron Lett., 36, 2377 (1995). Boronic acids and boronic esters are oxidized to phenols under similar conditions: Tetrahedron Lett., 36, 5117 (1995). Secondary amines are converted to nitroxide radicals in the presence of acetone and a phosphate buffer: Tetrahedron Lett., 36, 5547 (1995). Preferred co-oxidant for generation of dioxiranes from ketones; see Acetone, L10407. For use in a practical epoxidation of olefins using acetone in EtOAc-H₂O, see: Org. Process. Res. Dev., 6, 405 (2002).
• For a brief feature on the reagent, see: Synlett, 1178 (2002).
• Oxone is a registered trademark of E. I. Dupont de Nemours & Co., Inc.