Tri-n-butyltin deuteride

• Catalog No.: 88474
• CAS Number: 6180-99-0
• M. F.: C12H28Sn
• M. W.: 291.05172
• Purity: 96%

SYNONYMS

• Title: 氘代三正丁基锡
• IUPAC name: tributyl(^2H)stannane
• IUPAC Traditional name: tributyl(^2H)stannane
• Synonyms: Deutero tri-n-butylstannane

DATABASE IDS

• EC Number: 211-704-4
• MDL Number: MFCD00064886
• CAS Number: 6180-99-0

PROPERTIES

• TSCA Listed: 否
• Hazard Class: 6.1
• UN Number: UN2929
• Packing Group: II
• GHS Hazard statements: H301-H312-H315-H319-H372-H226-H400-H410
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• GHS Precautionary statements: P280-P273-P309-P310-P501A
• Risk Statements: 10-21-25-36/38-48/23/25-50/53
• Safety Statements: 36/37/39-45-60-61
• Storage Warning: Air & Moisture Sensitive
• Purity: 96%
• Apperance: Liquid
• Boiling Point: 65°C/0.6mm
• Density: 1.103
• Flash Point: 40°C(104°F)
• Refractive Index: 1.4720

REFERENCES

• Reducing agent, cf Tri-n-butyltin hydride, A13298, providing a convenient means of preparing specifically-deuterated compounds from the corresponding halide.
• Used in combination with the catalyst derived from (R)- or (S)-BINOL and Ti(O-i-Pr)₄ for the asymmetric reduction of aldehydes to chiral monodeutero primary alcohols (RCHDOH): J. Org. Chem., 61, 7638 (1996).