Cobalt(II) phthalocyanine

• Catalog No.: 41496
• CAS Number: 3317-67-7
• M. F.: C32H16CoN8
• M. W.: 571.45624

SYNONYMS

• Title: 酞菁钴(II)
• IUPAC name: λ^2-cobalt(2+) ion 2,11,20,29,37,38,39,40-octaazanonacyclo[28.6.1.1^3,^1^0.1^1^2,^1^9.1^2^1,^2^8.0^4,^9.0^1^3,^1^8.0^2^2,^2^7.0^3^1,^3^6]tetraconta-1(36),2,4,6,8,10(40),11,13,15,17,19,21(38),22,24,26,28,30,32,34-nonadecaene-37,39-diide
• IUPAC Traditional name: λ^2-cobalt(2+) ion 2,11,20,29,37,38,39,40-octaazanonacyclo[28.6.1.1^3,^1^0.1^1^2,^1^9.1^2^1,^2^8.0^4,^9.0^1^3,^1^8.0^2^2,^2^7.0^3^1,^3^6]tetraconta-1(36),2,4,6,8,10(40),11,13,15,17,19,21(38),22,24,26,28,30,32,34-nonadecaene-37,39-diide
• Synonyms: Phthalocyanine cobalt(II) salt

DATABASE IDS

• EC Number: 222-012-7
• CAS Number: 3317-67-7
• MDL Number: MFCD00010718

PROPERTIES

• Apperance: Powder
• GHS Hazard statements: H341-H317
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P280-P302+P352-P321-P405-P501A
• Risk Statements: 43-68
• Safety Statements: 36/37-60
• TSCA Listed: 是

REFERENCES

• Catalyzes the reduction of alkenes, alkyl halides, nitro and nitroso groups with sodium borohydride in ethanol: Angew. Chem. Int. Ed., 20, 473 (1981).
• Readily forms crystalline Li or Na anions. The Li anion can be used for the selective reduction of both aliphatic and aromatic nitro groups to amines in the presence of olefinic, nitrile, carbonyl or aryl halide functionality. The reaction is useful in the Friedlaender quinoline synthesis, in which an ortho-nitro benzaldehyde is reduced in situ and reacted with an ɑ-methylene ketone: Angew. Chem. Int. Ed., 20, 208 (1981).