Indium(III) bromide, anhydrous

• Catalog No.: 40126
• CAS Number: 13465-09-3
• M. F.: Br3In
• M. W.: 354.53
• Purity: 99.99% (metals basis)

SYNONYMS

• Title: 溴化铟(III), 无水
• IUPAC name: indium(3+) ion tribromide
• IUPAC Traditional name: indium(3+) ion tribromide

DATABASE IDS

• EC Number: 236-692-8
• CAS Number: 13465-09-3
• MDL Number: MFCD00011057

PROPERTIES

• Purity: 99.99% (metals basis)
• Apperance: Crystalline Powder
• Density: 4.74
• Melting Point: ca 436°C
• GHS Hazard statements: H314-H318
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• Risk Statements: 34
• Safety Statements: 26-36/37/39-45
• Storage Warning: Hygroscopic
• TSCA Listed: 是
• Hazard Class: 8
• UN Number: UN3260
• Packing Group: III

REFERENCES

• Versatile water-tolerant Lewis acid catalyst. Examples of its use include:
• Dithioacetalization of aldehydes in non-aqueous amd aqueous media: Tetrahedron Lett., 41, 9695 (2000). Addition of TMS cyanide to ɑ-hetero substituted ketones: Tetrahedron Lett., 42, 3041 (2001). Conversion of oxiranes to thiiranes with KSCN: Synlett, 396 (2003). Addition of indoles to enones: J. Org. Chem., 67, 3700 (2002); 68, 7126 (2003), and to chiral epoxides: J. Org. Chem., 67, 5386 (2002).
• For a brief feature on uses of the reagent in synthesis, see: Synlett, 711 (2005).