Carbonylchlorobis(triphenylphosphine)rhodium(I)

• Catalog No.: 39822
• CAS Number: 13938-94-8
• M. F.: C37H30ClOP2Rh
• M. W.: 690.939522
• Purity: Rh 14.9% min

SYNONYMS

• Title: 羰基氯双(三苯基磷基)铑(I)
• IUPAC name: (rhodiomethylidyne)oxidanium bis(triphenylphosphane) chloride
• IUPAC Traditional name: (rhodiomethylidyne)oxidanium bis(triphenylphosphine) chloride
• Synonyms: Carbonylbis(triphenylphosphine)rhodium(I) chloride

DATABASE IDS

• MDL Number: MFCD00044273
• CAS Number: 13938-94-8
• EC Number: 237-712-8

PROPERTIES

• Purity: Rh 14.9% min
• Apperance: Crystalline
• Solubility: Soluble in acetone, chloroform, ethanol
• GHS Hazard statements: H301-H311-H332
• European Hazard Symbols: X
• GHS Precautionary statements: P261-P301+P310-P361-P302+P352-P405-P501A
• Risk Statements: 20/21/22
• Safety Statements: 9-36/37-60
• TSCA Listed: 否

REFERENCES

• Catalyst for the decarbonylation of aldehydes and acyl halides: J. Am. Chem. Soc., 89, 2338 (1967); 90, 99 (1968); Tetrahedron Lett., 4713 (1966).
• Effective catalyst for the high-yield, stereoselective chloroesterification of terminal alkynes with alkyl chloroformates: J. Am. Chem. Soc., 120, 12365 (1998):