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(Ferrocenylmethyl)trimethylammonium iodide_Molecular_structure_CAS_12086-40-7)
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(Ferrocenylmethyl)trimethylammonium iodide

Catalog No. 39399 Name Alfa Aesar
CAS Number 12086-40-7 Website
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SYNONYMS

Title
(二茂铁基甲基)三甲基碘化铵
IUPAC name
λ2-iron(2+) ion 3-[(trimethylazaniumyl)methyl]cyclopenta-2,4-dien-1-ide cyclopenta-2,4-dien-1-ide iodide
IUPAC Traditional name
λ2-iron(2+) ion 3-[(trimethylammonio)methyl]cyclopenta-2,4-dien-1-ide cyclopentadienide iodide
Synonyms
N,N-Dimethylaminomethylferrocene methiodide

DATABASE IDS

EC Number 235-152-9
MDL Number MFCD00041534
CAS Number 12086-40-7

PROPERTIES

Apperance Crystalline
Melting Point 220°C dec.
TSCA Listed

DETAILS

REFERENCES

  • Intermediate for attachment of ferrocene units to secondary amines; thus reaction with 1,4,8,11-Tetraazacyclotetradecane, A11516, in the presence of K2CO3 in MeCN gives the tetrakis(ferrocenylmethyl) substituted cyclam, which is of interest as a ligand in Cu(I)-Cu(II) redox systems: J. Chem. Soc., Dalton, 2485 (1991). Self-assembly processes of Ni(II) ions with this ligand have been studied. The coordination of Ni(II) results in the formation of a host molecule containing a redox-active cavity, of potential use in electrocatalysis: J. Chem. Soc., Chem. Commun., 1643 (1995).