Iodine monochloride

• Catalog No.: 39104
• CAS Number: 7790-99-0
• M. F.: ClI
• M. W.: 162.35747

SYNONYMS

• Title: 单氯化碘
• IUPAC name: iodochlorane
• IUPAC Traditional name: iodine monochloride
• Synonyms: Chloroiodide

DATABASE IDS

• Beilstein Number: 3902972
• Merck Index: 145017
• EC Number: 232-236-7
• CAS Number: 7790-99-0
• MDL Number: MFCD00011354

PROPERTIES

• Apperance: Crystalline/Liquid
• Boiling Point: 96-98°C
• Density: 3.1822
• Melting Point: 25-27°C
• Solubility: Soluble in water, alcohol, ether, carbon disulfide
• GHS Hazard statements: H314-H318-H302-H312
• European Hazard Symbols: X
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P280-P303+P361+P353-P305+P351+P338-P310
• Risk Statements: 21/22-34
• RTECS: NN1650000
• Safety Statements: 26-36/37/39-45
• Storage Warning: Moisture & Light Sensitive
• TSCA Listed: 是
• Hazard Class: 8
• UN Number: UN1792
• Packing Group: II

REFERENCES

• More powerful electrophilic iodinating agent than iodine e.g. for aromatic substitution. For examples of its use in AcOH for aromatic iodination, see: Org. Synth. Coll., 2, 196, 343 (1943).
• The 1:1 complex with pyridine has been recommended as a mild and efficient iodinating agent for a wide range aromatic compounds: J. Chem. Res., 405 (1994). Condensed polycyclic iodides which cannot readily be prepared by direct iodination methods are formed by reaction of the same complex with the organomercurials: J. Chem. Res. (Synop.), 405 (1995).
• For use in combination with NaN₃ for the iodoazidation of an olefin, see: Org. Synth. Coll., 6, 893 (1988).
• Reacts with Benzyltrimethylammonium chloride, A16759 to form benzyltrimethylammonium dichloroiodide, a useful reagent for the iodination of phenols: Chem. Lett., 2109 (1987).