Chloro(1,5-cyclooctadiene)iridium(I) dimer

• Catalog No.: 12749
• CAS Number: 12112-67-3
• M. F.: C16H24Cl2Ir2
• M. W.: 671.70176
• Purity: Ir 57.2%

SYNONYMS

• Title: (1,5-环辛二烯)二氯化铱(I)二聚体
• IUPAC name: bis(chloroiridium); bis(cycloocta-1,5-diene)
• IUPAC Traditional name: bis(1,5-cyclooctadiene); bis(chloroiridium)
• Synonyms: Bis(1,5-cyclooctadiene)diiridium(I) dichloride

DATABASE IDS

• EC Number: 235-170-7
• MDL Number: MFCD00012414
• CAS Number: 12112-67-3

PROPERTIES

• Purity: Ir 57.2%
• Apperance: Crystalline powder
• Melting Point: 190°C dec.
• Solubility: Soluble in chloroform, toluene. Slightly soluble in acetone, alcohol.
• TSCA Listed: 否

REFERENCES

• Catalyst precursor for asymmetric hydrogenation: Angew. Chem. Int. Ed., 37, 2897 (1998).
• Effective catalyst for the reaction of alcohols with vinyl acetate to give vinyl ethers: J. Am. Chem. Soc., 124, 1590 (2002).
• With catalytic amounts of dppp (1,3-Bis(diphenylphosphino)propane, A12931) and Cs₂CO₃, a transfer hydrogenation system with 2-propanol as the H source can reduce both olefinic double bonds and carbonyl groups; for ɑ?-unsaturated ketones, selective reduction to saturated ketones can be achieved: J. Org. Chem., 66, 4710 (2001).
• In the presence of a phosphite, catalyzes displacements by carbon nucleophiles at the more substituted position in allylic systems: Angew Chem. Int. Ed., 36, 263 (1997); J. Am. Chem. Soc., 120, 8647 (1998).
• Catalyst for Miyaura and Hartwig's direct boronylation of arenes with Bis(pinacolato)diboron, L16088: J. Am. Chem. Soc., 124, 390 (2002):