Iron(III) nitrate nonahydrate

• Catalog No.: 12226
• CAS Number: 7782-61-8
• M. F.: FeH18N3O18
• M. W.: 403.99722
• Purity: 98+% (metals basis)

SYNONYMS

• Title: 硝酸铁(III) 九水合物
• IUPAC name: iron(3+) ion nonahydrate trinitrate
• IUPAC Traditional name: iron(3+) ion nonahydrate trinitrate

DATABASE IDS

• Merck Index: 144027
• CAS Number: 7782-61-8
• MDL Number: MFCD00149708
• EC Number: 233-899-5

PROPERTIES

• Purity: 98+% (metals basis)
• Apperance: Crystalline, Contains excess HNO3
• Boiling Point: 125°C dec.
• Density: 1.684
• Melting Point: 47°C
• GHS Hazard statements: H272-H315-H319
• European Hazard Symbols: Irritant (Xi)
• European Hazard Symbols: Oxidising (O)
• GHS Precautionary statements: P221-P210-P305+P351+P338-P302+P352-P321-P501A
• Risk Statements: 8-36/38
• RTECS: NO7175000
• Safety Statements: 17-26-37-60
• Storage Warning: Moisture Sensitive
• TSCA Listed: 是
• Hazard Class: 5.1
• UN Number: UN1466
• Packing Group: III

REFERENCES

• Catalyst for preparation of alkali metal amides from the metals in liquid ammonia (numerous Organic Syntheses references).
• On a clay support, cleaves 2,4-dinitrophenylhydrazones: Synthesis, 439 (1985).
• For use in regioselective mononitration of phenols, see: Tetrahedron, 45, 1415 (1989). The reaction can also be carried out in an ionic liquid: Synth. Commun., 33, 961 (2003).
• Details have been given for an improved method for preparation of the useful oxidizing agent potassium ferrate(VI) by oxidation with hypochlorite, and subsequent use, supported on Montmorillonite K10 clay, for the selective oxidation of benzyl alcohol or benzylamine to benzaldehyde, thiols to disulfides, aniline to azobenzene and various oximes and hydrazones to the parent ketone: J. Org. Chem., 61, 6360 (1996).