Dodecacarbonyltriruthenium

• Catalog No.: 10507
• CAS Number: 15243-33-1
• M. F.: C12O12Ru3
• M. W.: 639.3312
• Purity: 99%

SYNONYMS

• Title: 十二羰基三钌
• IUPAC name: dodecakis(methanidylidyneoxidanium) triruthenium
• IUPAC Traditional name: dodecakis(carbon monoxide) triruthenium
• Synonyms: Ruthenium carbonyl; Triruthenium dodecacarbonyl

DATABASE IDS

• EC Number: 239-287-4
• CAS Number: 15243-33-1
• MDL Number: MFCD00011209

PROPERTIES

• Purity: 99%
• Apperance: Crystalline
• Melting Point: ca 150°C dec.
• Solubility: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating
• GHS Hazard statements: H331
• European Hazard Symbols: Toxic (T)
• GHS Precautionary statements: P261-P321-P304+P340-P311-P405-P501A
• Risk Statements: 23
• Safety Statements: 9-36-45-60
• TSCA Listed: 是
• Hazard Class: 6.1
• UN Number: UN3466
• Packing Group: III

REFERENCES

• 1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):
  
• On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.