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Dodecacarbonyltriruthenium

Catalog No. 10507 Name Alfa Aesar
CAS Number 15243-33-1 Website
M. F. C12O12Ru3 Telephone
M. W. 639.3312 Fax
Purity 99% Email
Storage Chembase ID: 147959

SYNONYMS

Title
十二羰基三钌
IUPAC name
dodecakis(methanidylidyneoxidanium) triruthenium
IUPAC Traditional name
dodecakis(carbon monoxide) triruthenium
Synonyms
Ruthenium carbonyl
Triruthenium dodecacarbonyl

DATABASE IDS

EC Number 239-287-4
CAS Number 15243-33-1
MDL Number MFCD00011209

PROPERTIES

Purity 99%
Apperance Crystalline
Melting Point ca 150°C dec.
Solubility Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, benzene) and acetone. Solutions undergo some decomposition on strong heating
GHS Pictograms GHS06
GHS Hazard statements H331
European Hazard Symbols Toxic Toxic (T)
GHS Precautionary statements P261-P321-P304+P340-P311-P405-P501A
Risk Statements 23
Safety Statements 9-36-45-60
TSCA Listed
Hazard Class 6.1
UN Number UN3466
Packing Group III

DETAILS

REFERENCES

  • 1,6-Enynes undergo cyclocondensation with CO under pressure, to give bicyclo[3.3.0]octenones: J. Org. Chem., 62, 3762 (1997):
  • On heating under pressure with norbornene and CO, alkynes undergo aromatization to give condensed hydroquinones: Organometallics, 17, 766 (1998). For reaction scheme, see 2-Hexyne, B22405.