Chloro(1,5-cyclooctadiene)rhodium(I) dimer

• Catalog No.: 10466
• CAS Number: 12092-47-6
• M. F.: C16H24Cl2Rh2
• M. W.: 493.07876

SYNONYMS

• Title: (1,5-环辛二烯)氯化铑(I)二聚体
• IUPAC name: bis(chlororhodium); bis(cycloocta-1,5-diene)
• IUPAC Traditional name: bis(1,5-cyclooctadiene); bis(chlororhodium)
• Synonyms: Bis(1,5-cyclooctadiene)dirhodium(I) dichloride

DATABASE IDS

• EC Number: 235-157-6
• CAS Number: 12092-47-6
• MDL Number: MFCD00012415

PROPERTIES

• Apperance: Crystalline
• Melting Point: 243°C dec.
• Solubility: Sparingly soluble in most common solvents
• Storage Warning: Air Sensitive & Hygroscopic
• TSCA Listed: 是

REFERENCES

• Homogeneous catalyst and catalyst precursor. For use in the preparation of a chiral BINAP alkene isomerization catalyst, see: Org. Synth. Coll., 8, 183 (1993).
• Catalyzes the dehydrogenative coupling reaction of styrenes with Pinacolborane, L17558 to give the corresponding vinylboronates: Tetrahedron Lett., 40, 2585 (1999); Bull. Chem. Soc. Jpn., 75, 825 (2002). The complex has also been found to promote the atmospheric pressure carbonylation of benzylic halides to give good yields of phenylacetic acids: Tetrahedron Lett., 41, 7601 (2000).
• Miyaura has reported the Rh-catalyzed conjugate addition of arylboronic acids to ɑ?-unsaturated carbonyl compounds in a single aqueous phase: Chem. Lett., 722 (2001):