Allylpalladium(II) chloride dimer

• Catalog No.: 10005
• CAS Number: 12012-95-2
• M. F.: C6H10Cl2Pd2
• M. W.: 365.8896
• Purity: Pd 56.0% min

SYNONYMS

• Title: 烯丙基氯化钯(II)二聚体
• IUPAC name: bis(chloro(prop-2-en-1-yl)palladium)
• IUPAC Traditional name: bis(chloro(prop-2-en-1-yl)palladium)
• Synonyms: Bis(allyl)dichlorodipalladium(II)

DATABASE IDS

• MDL Number: MFCD00044874
• EC Number: 234-579-8
• CAS Number: 12012-95-2
• Beilstein Number: 4124623

PROPERTIES

• Purity: Pd 56.0% min
• Apperance: Powder
• Melting Point: 120°C dec.
• Solubility: Very soluble in dichloromethane and dichloroethane. Slightly soluble in toluene, insoluble in water
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• RTECS: RT3510000
• Safety Statements: 26-37-60
• Storage Warning: Air & Moisture Sensitive
• TSCA Listed: 否

REFERENCES

• Reacts with lithium enolates of esters, in the presence of CO and excess TMEDA, to give good yields of ɑ-cyclopropyl esters: Angew. Chem. Int. Ed., 31, 234 (1992).
• Used in combination with a chiral diamine to effect displacement of a mesylate with Trimethylsilyl azide, L00173, in the asymmetric synthesis of (+)-pancratistin: J. Am. Chem. Soc., 117, 10143 (1995).