Samarium(III) trifluoromethanesulfonate

• Catalog No.: L20253
• CAS Number: 52093-28-4
• M. F.: C3F9O9S3Sm
• M. W.: 597.5673288
• Purity: 98%

SYNONYMS

• Title: 三氟甲烷磺酸钐(III)
• IUPAC name: samarium(3+) ion tritrifluoromethanesulfonate
• IUPAC Traditional name: samarium(3+) ion tritriflate
• Synonyms: Samarium(III) triflate

DATABASE IDS

• MDL Number: MFCD00192431
• EC Number: 000-000-0
• CAS Number: 52093-28-4

PROPERTIES

• Purity: 98%
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• Storage Warning: Hygroscopic
• TSCA Listed: 否

REFERENCES

• Effective catalyst for the Baylis-Hillman reaction, using 1,4-Diazabicyclo[2.2.2]octane, A14003: J. Org. Chem., 63, 7183 (1998). The uses of rare-earth metal triflates in organic synthesis have been reviewed by S. Kobayashi: Synlett, 689 (1994); Chem. Rev., 102, 2227 (2002).