Triphenylphosphine, polymer-supported, 1.4-2.0 mmol/g on polystyrene

• Catalog No.: L19478
• M. F.: C18H14P
• M. W.: 261.277521

SYNONYMS

• Title: 三苯基膦, 聚合物负载, 1.4-2.0 mmol/g于聚苯乙烯

DATABASE IDS

• MDL Number: MFCD00148025

PROPERTIES

• GHS Hazard statements: H301-H317-H413
• European Hazard Symbols: X
• GHS Precautionary statements: P261-P301+P310-P302+P352-P321-P405-P501A
• Risk Statements: 22-43-53
• Safety Statements: 24-37-60-61
• TSCA Listed: 否

REFERENCES

• Support for nickel, rhenium and rhodium in hydrogenation: J. Am. Chem. Soc., 97, 1742 (1975); dimerization of alkenes: J. Am. Chem. Soc., 97, 341 (1974) and hydroformylation: J. Am. Chem. Soc., 98 5402 (1976). For the halogenation of carboxylic acid and alkanes in carbon tetrachloride: Synthesis, 1093 (1992). Addition of iodine in DMF esterifies primary and secondary alcohols to their respective formate esters: Med. Res. Rev., 19, 97 (1999).
• For use in the Mitsunobu reaction: Tetrahedron Lett., 8751 (1998), and the Wittig reaction: J. Org. Chem., 48, 326 (1983); J. Chem. Soc. Perkin 1, 2243 (1998).