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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine_Molecular_structure_CAS_133407-38-2)
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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine

Catalog No. L19413 Name Alfa Aesar
CAS Number 133407-38-2 Website
M. F. C14H25NOSi Telephone
M. W. 251.4399 Fax
Purity tech. 85% Email
Storage Chembase ID: 302587

SYNONYMS

Title
(R)-(+)-N-甲氧基甲基-N-(三甲基甲硅基)甲基-1-苯乙胺
IUPAC name
(methoxymethyl)[(1S)-1-phenylethyl][(trimethylsilyl)methyl]amine
IUPAC Traditional name
(methoxymethyl)[(1S)-1-phenylethyl][(trimethylsilyl)methyl]amine

DATABASE IDS

CAS Number 133407-38-2
MDL Number MFCD06798959
Beilstein Number 4745464

PROPERTIES

Purity tech. 85%
Boiling Point 82-84°C/0.2mm
Density 0.926
Optical Rotation +47 (c=1 in carbon tetrachloride)
Refractive Index 1.4930
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
Safety Statements 26-37
Storage Warning Moisture Sensitive
TSCA Listed

DETAILS

REFERENCES

  • The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362(1996).