(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine

• Catalog No.: L19413
• CAS Number: 133407-38-2
• M. F.: C14H25NOSi
• M. W.: 251.4399
• Purity: tech. 85%

SYNONYMS

• Title: (R)-(+)-N-甲氧基甲基-N-(三甲基甲硅基)甲基-1-苯乙胺
• IUPAC name: (methoxymethyl)[(1S)-1-phenylethyl][(trimethylsilyl)methyl]amine
• IUPAC Traditional name: (methoxymethyl)[(1S)-1-phenylethyl][(trimethylsilyl)methyl]amine

DATABASE IDS

• CAS Number: 133407-38-2
• MDL Number: MFCD06798959
• Beilstein Number: 4745464

PROPERTIES

• Purity: tech. 85%
• Boiling Point: 82-84°C/0.2mm
• Density: 0.926
• Optical Rotation: +47 (c=1 in carbon tetrachloride)
• Refractive Index: 1.4930
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• Storage Warning: Moisture Sensitive
• TSCA Listed: 否

REFERENCES

• The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362(1996).