Dibenzyl azodicarboxylate

• Catalog No.: L19347
• CAS Number: 2449-05-0
• M. F.: C16H14N2O4
• M. W.: 298.29336
• Purity: 96%

SYNONYMS

• Title: 偶氮二羟酸二苄酯
• IUPAC name: N-{[(benzyloxy)carbonyl]imino}(benzyloxy)formamide
• IUPAC Traditional name: N-{[(benzyloxy)carbonyl]imino}benzyloxyformamide
• Synonyms: DBAD; Azodicarboxylic acid dibenzyl ester

DATABASE IDS

• CAS Number: 2449-05-0
• EC Number: 219-508-0
• Beilstein Number: 2298734
• MDL Number: MFCD00016737

PROPERTIES

• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• TSCA Listed: 是
• Purity: 96%
• Flash Point: >110°C(230°F)
• Melting Point: 43-47°C

REFERENCES

• For the formation of functionalized ?-amino alcohols by the three-component asymmetric assembly with an aldehyde and a ketone, see: Org. Lett, 5, 1685 (2003).
• Aza-dienophile; the cycloaddition products can be debenzylated by hydrogenolysis: J. Am. Chem. Soc., 109, 285 (1987); 110, 5229 (1988); 111, 2995 (1989). Compare Di-tert-butyl azodicarboxylate, L00294, Diethyl azodicarboxylate, L19348, and Diisopropyl azodicarboxylate, L10386. Effects enantioselective ɑ-amination of aldehydes, mediated by L-Proline, A10199: J. Am. Chem. Soc., 124, 5656 (2002):