1-n-Butyl-3-methylimidazolium hexafluorophosphate

• Catalog No.: L19086
• CAS Number: 174501-64-5
• M. F.: C8H15F6N2P
• M. W.: 284.1822802
• Purity: 98+%

SYNONYMS

• Title: 1-正-丁基-3-甲基咪唑鎓六氟磷酸盐
• IUPAC name: 1-butyl-3-methyl-1H-imidazol-3-ium; hexafluoro-λ^5-phosphanuide
• IUPAC Traditional name: 1-butyl-3-methylimidazolium hexafluorophosphate
• Synonyms: BMIMPF6

DATABASE IDS

• CAS Number: 174501-64-5
• EC Number: 000-000-0
• Merck Index: 141581
• MDL Number: MFCD03093295

PROPERTIES

• Purity: 98+%
• Boiling Point: >350°C
• Density: 1.365
• Melting Point: 8-10°C
• Refractive Index: 1.4115
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• TSCA Listed: 否

REFERENCES

• A copper-free Sonogashira coupling of terminal alkynes with aryl iodides, catalyzed by trans-Dichlorobis(triphenylphosphine)palladium(II), 10491, has been adapted to a microflow system for efficient catalyst recycling: Org. Lett., 4, 1691 (2002).
• Ionic liquid.
• For use in dihydroxylation of alkenes with Osmium(VIII) oxide, 12103, facilitating the reuse of the Os catalyst, see: Org. Lett., 4, 2197 (2002).
• Recyclable medium for oxidation of alcohols, catalyzed by TEMPO, A12733, and CuCl, to give aldehydes and ketones chemoselectively under mild conditions: Org. Lett., 4, 1507 (2002).
• Heck reactions with aryl halides can be carried out with controlled microwave heating: J. Org. Chem., 67, 6243 (2002).