Ishikawa's Reagent

• Catalog No.: L16738
• CAS Number: 309-88-6
• M. F.: C7H11F6N
• M. W.: 223.1593592
• Purity: 90+%

SYNONYMS

• Title: 石川试剂
• IUPAC name: diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
• IUPAC Traditional name: diethyl(1,1,2,3,3,3-hexafluoropropyl)amine
• Synonyms: N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine

DATABASE IDS

• MDL Number: MFCD00054683
• CAS Number: 309-88-6

PROPERTIES

• Purity: 90+%
• Boiling Point: 56-57°C/58mm
• Density: 1.230
• Flash Point: 14°C(57°F)
• Refractive Index: 1.3500
• GHS Hazard statements: H225-H314-H318
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-34
• Safety Statements: 16-26-36/37/39-45
• TSCA Listed: 否
• Hazard Class: 3
• UN Number: UN2924
• Packing Group: II

REFERENCES

• For use in conversion, in ether or THF, of alcohols to alkyl fluorides, see: Bull. Chem. Soc. Jpn., 52, 3377 (1979); J. Fluorine Chem., 31, 135 (1986); 38, 243 (1988). Addition of NaF as a scavenger of the HF liberated in the reaction gives improved results: J. Fluorine Chem., 23, 383 (1983). Carboxylic acids are converted to acyl fluorides: Bull. Chem. Soc. Jpn., 52, 3377 (1979).
• A mixture of N,N-Diethyl-1,1,2,3,3,3-hexafluoropropylamine and N,N-Diethyl-1,2,3,3,3-pentafluoropropenamine, both of which are active fluorinating agents.