Borane-morpholine complex

• Catalog No.: L15110
• CAS Number: 4856-95-5
• M. F.: C4H12BNO
• M. W.: 100.95518
• Purity: 97%

SYNONYMS

• Title: 硼烷-吗啉,络合物 97%
• IUPAC name: morpholine borane
• IUPAC Traditional name: morpholine borane
• Synonyms: Morpholine borane

DATABASE IDS

• CAS Number: 4856-95-5
• MDL Number: MFCD00066736
• EC Number: 225-450-7

PROPERTIES

• Purity: 97%
• Melting Point: 93-95°C
• GHS Hazard statements: H228-H301-H314-H318
• European Hazard Symbols: X
• European Hazard Symbols: Corrosive (C)
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P301+P310-P303+P361+P353-P305+P351+P338-P405-P501A
• Risk Statements: 11-22-34
• RTECS: QD8530000
• Safety Statements: 16-26-36/37/39-45
• TSCA Listed: 是
• Hazard Class: 4.1
• UN Number: UN2925
• Packing Group: II

REFERENCES

• Selective reducing agent. Reactivity in carbonyl reductions is increased in acidic media: J. Am. Chem. Soc., 92, 4203 (1970); J. Chem. Soc., Perkin 2, 1948 (1973). For a review of amine boranes as selective reducing and hydroborating agents, see: Org. Prep. Proced. Int., 16, 335 (1984).
• Treatment with n-BuLi generates the lithium aminoborohydride, a powerful reducing agent similar to LiAH₄ in its reducing power, but air-stable and non-pyrophoric: J. Org. Chem., 59, 6378 (1994).