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Diethylmethoxyborane, 1M soln in THF_Molecular_structure_CAS_7397-46-8)
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Diethylmethoxyborane, 1M soln in THF

Catalog No. L15107 Name Alfa Aesar
CAS Number 7397-46-8 Website
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Storage Chembase ID: 138674

SYNONYMS

Title
二乙基甲氧基硼烷, 1M THF溶液
IUPAC name
methyl diethylborinate
IUPAC Traditional name
methyl diethylborinate

DATABASE IDS

CAS Number 7397-46-8
MDL Number MFCD00013240
Beilstein Number 2231225

PROPERTIES

Concentration 1M soln in THF
Density 0.868
Flash Point -6°C(21°F)
Refractive Index 1.4040
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS06
GHS Hazard statements H225-H301-H314-H318
European Hazard Symbols X
European Hazard Symbols Corrosive Corrosive (C)
European Hazard Symbols Flammable Flammable (F)
GHS Precautionary statements P210-P280-P305+P351+P338-P309-P310
Risk Statements 11-19-22-34
RTECS ED6151000
Safety Statements 16-26-36/37/39-45
Storage Warning Air & Moisture Sensitive
TSCA Listed
Hazard Class 3
UN Number UN2924
Packing Group II

DETAILS

REFERENCES

  • Has been used in combination with sodium borohydride for selective reductions: ?-hydroxy ketones are reduced with high diastereoselectivity to syn-diols: Tetrahedron Lett., 28, 155 (1987); ? δ-diketo esters are reduced to ? δ-dihydroxy esters without reduction of a conjugated olefinic double bond: Tetrahedron Lett., 29, 6467 (1988).