(S)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene

• Catalog No.: L14583
• CAS Number: 112022-81-8
• M. F.: C18H20BNO
• M. W.: 277.1685

SYNONYMS

• Title: (S)-2-甲基-CBS-氧杂硼啶, 1M 甲苯溶液
• IUPAC name: (3aS)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole
• IUPAC Traditional name: (3aS)-1-methyl-3,3-diphenyl-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
• Synonyms: (S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

DATABASE IDS

• CAS Number: 112022-81-8
• MDL Number: MFCD00078439

PROPERTIES

• Concentration: 1M soln. in toluene
• Density: 0.925
• Flash Point: 4°C(39°F)
• GHS Hazard statements: H224-H304-H361-H373-H332-H315-H336
• European Hazard Symbols: X
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P301+P310-P303+P361+P353-P405-P501A
• Risk Statements: 11-20-38-48/20-63-65-67
• Safety Statements: 36/37-46-62
• Storage Warning: Air & Moisture Sensitive
• TSCA Listed: 否
• Hazard Class: 3
• UN Number: UN1993
• Packing Group: II

REFERENCES

• Anhydrous catalyst for 'CBS' reduction reaction. For examples of use in asymmetric reduction of ketones, see: Org. Synth. Coll., 9, 362, 676 (1998). For further information, see (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219.