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Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4_Molecular_structure_CAS_14044-65-6)
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Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4

Catalog No. L13961 Name Alfa Aesar
CAS Number 14044-65-6 Website
M. F. C4H11BO Telephone
M. W. 85.94054 Fax
Purity Email
Storage Chembase ID: 136015

SYNONYMS

Title
四氢呋喃硼烷,1M 在四氢呋喃溶剂中,以5mmol NaBH
IUPAC name
oxolane borane
IUPAC Traditional name
tetrahydrofuran borane
Synonyms
BTHF

DATABASE IDS

EC Number 237-881-8
Beilstein Number 3668402
CAS Number 14044-65-6
MDL Number MFCD00012429

PROPERTIES

Concentration 1M soln. in THF
Density 0.878
Flash Point -21°C(-8°F)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Hazard statements H225-H260-H318-H315-H351-H335-H303
European Hazard Symbols Irritant Irritant (Xi)
European Hazard Symbols Flammable Flammable (F)
GHS Precautionary statements P210-P231+P232-P303+P361+P353-P305+P351+P338-P405-P501A
Risk Statements 11-14/15-19-37/38-41
Safety Statements 7/8-9-16-23-26-30-33-36/37/39-43-60
Storage Warning Air & Moisture Sensitive
TSCA Listed
Hazard Class 4.3
UN Number UN3148
Packing Group I

DETAILS

REFERENCES

  • Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7,339 (1990).
  • For other reactions of borane, see Borane-dimethyl sulfide complex, L07705.
  • Examples of hydroboration reactions:
  • For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).