Isopentyl nitrite

• Catalog No.: L13909
• CAS Number: 110-46-3
• M. F.: C5H11NO2
• M. W.: 117.14634
• Purity: 97%, stab. with 0.2% anhyd. sodium carbonate

SYNONYMS

• Title: 亚硝酸异戊酯
• IUPAC name: 3-methylbutyl nitrite
• IUPAC Traditional name: aspiral
• Synonyms: Isoamyl nitrite; Amyl nitrite

DATABASE IDS

• CAS Number: 110-46-3
• MDL Number: MFCD00002057
• Beilstein Number: 969510
• Merck Index: 145123
• EC Number: 203-770-8

PROPERTIES

• Purity: 97%, stab. with 0.2% anhyd. sodium carbonate
• Boiling Point: 95-100°C
• Density: 0.875
• Flash Point: -20°C(-4°F)
• Refractive Index: 1.3870
• GHS Hazard statements: H225-H331-H302
• European Hazard Symbols: X
• European Hazard Symbols: Flammable (F)
• GHS Precautionary statements: P210-P241-P303+P361+P353-P321-P405-P501A
• Risk Statements: 11-20/22
• RTECS: NT0187500
• Safety Statements: 16-24-46
• Storage Warning: Air & Light Sensitive
• TSCA Listed: 是
• Hazard Class: 3
• UN Number: UN1113
• Packing Group: II

REFERENCES

• Widely used in non-aqueous nitrosation and diazotization reactions.
• For aromatic arylation as an alternative to the Gomberg reaction, see: J. Chem. Soc., 4257 (1962). For deamination of arylamines using THF as a hydrogen donor, see: J. Chem. Soc., Perkin 1, 541 (1973).
• For use in the generation of benzyne from anthranilic acid, see: J. Org. Chem., 38, 3462 (1973).
• ɑ-Amino esters are converted to ɑ-diazo esters: Tetrahedron, 31, 227 (1975).
• For other reactions of alkyl nitrites, see Isobutyl nitrite, L05259, and tert-Butyl nitrite, L16135.