Tri(2-furyl)phosphine

• Catalog No.: L13329
• CAS Number: 5518-52-5
• M. F.: C12H9O3P
• M. W.: 232.171821
• Purity: 97%

SYNONYMS

• Title: 三(2-呋喃基)膦
• IUPAC name: tris(furan-2-yl)phosphane
• IUPAC Traditional name: tris(furan-2-yl)phosphane
• Synonyms: Tris(2-furyl)phosphine

DATABASE IDS

• CAS Number: 5518-52-5
• Beilstein Number: 1577564
• EC Number: 000-000-0
• MDL Number: MFCD00151857

PROPERTIES

• Purity: 97%
• Boiling Point: 136°C/4mm
• Melting Point: 59-64°C
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• TSCA Listed: 否

REFERENCES

• Best ligand for Pd-catalyzed coupling of 5-iodouracil and unsaturated tributylstannanes: Synlett, 157 (1991).
• Large rate enhancements (10 ² -10 ³ ) over triphenylphosphine are observed in Pd-catalyzed coupling of olefinic stannanes and electrophiles: J. Am. Chem. Soc ., 113, 9585 (1991).
• In a study of Pd-catalyzed coupling reactions in supercritical CO ₂, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, L06941.