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Barium manganate

Catalog No. L13172 Name Alfa Aesar
CAS Number 7787-35-1 Website
M. F. BaMnO4 Telephone
M. W. 256.262649 Fax
Purity tech. 90% Email
Storage Chembase ID: 147496

SYNONYMS

Title
钡锰酸盐
IUPAC name
barium(2+) ion dioxomanganesebis(olate)
IUPAC Traditional name
barium(2+) ion manganate

DATABASE IDS

Merck Index 14981
EC Number 232-109-6
MDL Number MFCD00011514
CAS Number 7787-35-1

PROPERTIES

Purity tech. 90%
Density 4.850
GHS Pictograms GHS03
GHS Pictograms GHS06
GHS Hazard statements H272-H331-H302
European Hazard Symbols X
European Hazard Symbols Oxidising Oxidising (O)
GHS Precautionary statements P221-P210-P220-P321-P405-P501A
Risk Statements 8-20/22
Safety Statements 9-17-36
Storage Warning Moisture Sensitive
TSCA Listed
Hazard Class 5.1
UN Number UN3087
Packing Group III

DETAILS

REFERENCES

  • Supported on alumina with copper(II) sulfate, benzylic, allylic and saturated secondary alcohols can be selectively oxidized in the presence of a saturated primary alcohol: Tetrahedron Lett., 30, 2559 (1989).
  • Reagent for the oxidation of primary and secondary alcohols to carbonyls: Tetrahedron Lett ., 839 (1978). Superior to manganese dioxide for the oxidation of a secondary allylic alcohol to the ketone: Synth. Commun., 9, 771 (1979), and also for the dehydrogenation of 2-imidazolines to imidazoles: Synthesis, 489 (1980).