N-Phenylbis(trifluoromethanesulfonimide)

• Catalog No.: L12531
• CAS Number: 37595-74-7
• M. F.: C8H5F6NO4S2
• M. W.: 357.2500192
• Purity: 99%

SYNONYMS

• Title: N-苯基双(三氟甲磺酰亚胺)
• IUPAC name: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• IUPAC Traditional name: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• Synonyms: Phenyl triflimide; N,N-Bis(trifluoromethanesulfonyl)aniline

DATABASE IDS

• CAS Number: 37595-74-7
• MDL Number: MFCD00000404
• Beilstein Number: 1269141

PROPERTIES

• Purity: 99%
• Melting Point: 100-102°C
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P261-P305+P351+P338-P302+P352-P321-P405-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37
• Storage Warning: Moisture Sensitive
• TSCA Listed: 否

REFERENCES

• Convenient reagent for preparation of triflates of phenols and amines: Tetrahedron Lett., 4607 (1973); Org. Lett., 4, 1231 (2002); or of enol triflates from carbonyl compounds: Tetrahedron Lett., 24, 979 (1983); J. Org. Chem., 51, 277 (1986). For discussion of the reactivity of triflates, see Trifluoromethanesulfonic anhydride, A11767.