(1R)-(-)-Menthyl chloroformate

• Catalog No.: L11739
• CAS Number: 14602-86-9
• M. F.: C11H19ClO2
• M. W.: 218.72036
• Purity: 95%

SYNONYMS

• Title: (1R)-(-)-薄荷基氯甲酸酯
• IUPAC name: (1R,2S,5R)-5-methyl-2-(propan-2-yl)cyclohexyl chloroformate
• IUPAC Traditional name: (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl chloroformate
• Synonyms: L-Menthyl chloroformate; Chloroformic acid (1R)-menthyl ester

DATABASE IDS

• Beilstein Number: 2414686
• MDL Number: MFCD00009694
• CAS Number: 14602-86-9

PROPERTIES

• Purity: 95%
• Boiling Point: 108-109°C/11mm
• Density: 1.025
• Flash Point: 70°C(158°F)
• Optical Rotation: -82 (c=1 in chloroform)
• Refractive Index: 1.4580
• GHS Hazard statements: H330-H314-H318-H227
• European Hazard Symbols: Toxic (T)
• GHS Precautionary statements: P210-P303+P361+P353-P304+P340-P305+P351+P338-P320-P405-P501A
• Risk Statements: 23-34
• Safety Statements: 4-9-20-26-36/37/39-45
• Storage Warning: Moisture Sensitive
• TSCA Listed: 否
• Hazard Class: 6.1
• UN Number: UN3277
• Packing Group: II

REFERENCES

• Chiral derivatizing agent for alcohols and amines, allowing separation by chromatographic or crystallization techniques. For use in the resolution of 1,1'-binaphthyl derivatives, see: J. Org. Chem., 60, 6599 (1995).