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Bis(trimethylsilylmethyl) sulfide

Catalog No. L10296 Name Alfa Aesar
CAS Number 4712-51-0 Website
M. F. C8H22SSi2 Telephone
M. W. 206.49628 Fax
Purity 96% Email
Storage Chembase ID: 152469

SYNONYMS

Title
双(三甲基硅基甲基)硫醚
IUPAC name
trimethyl({[(trimethylsilyl)methyl]sulfanyl}methyl)silane
IUPAC Traditional name
trimethyl({[(trimethylsilyl)methyl]sulfanyl}methyl)silane

DATABASE IDS

Beilstein Number 1740046
MDL Number MFCD00039797
CAS Number 4712-51-0

PROPERTIES

Purity 96%
Boiling Point 65-66°C/5mm
Density 0.844
Flash Point 65°C(149°F)
Refractive Index 1.4565
GHS Hazard statements H227
GHS Precautionary statements P210-P280-P370+P378A-P403+P235-P501A
TSCA Listed

DETAILS

REFERENCES

  • Behaves as a dimethyl sulfide anion equivalent in the F - promoted methylthiomethylation of aldehydes and ketones: Synlett, 557 (1991). Epoxides undergo regio- and enantioselective ring-opening, in the presence of TBAF, providing a straightforward route to 1,2-mercapto alcohols: Synlett, 3063 (2005).