(R)-2-Methyl-CBS-oxazaborolidine monohydrate

• Catalog No.: L09230
• CAS Number: 112022-83-0
• M. F.: C18H20BNO
• M. W.: 277.1685
• Purity: 94%

SYNONYMS

• Title: (R)-2-甲基-CBS-氧杂硼啶单水合物
• IUPAC name: (3aR)-1-methyl-3,3-diphenyl-hexahydropyrrolo[1,2-c][1,3,2]oxazaborole
• IUPAC Traditional name: (3aR)-1-methyl-3,3-diphenyl-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
• Synonyms: (R)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole

DATABASE IDS

• Beilstein Number: 9059874
• CAS Number: 112022-83-0
• MDL Number: MFCD00078440

PROPERTIES

• Purity: 94%
• Optical Rotation: +74 (c=1 in methanol)
• TSCA Listed: 否

REFERENCES

• Air-stable solid prepared by a modification of Corey's procedure, on which his literature results were based. For anhydrous reagent, see (R)-2-Methyl-CBS-oxazaborolidine, L14582.
• Chiral auxiliary for the highly enantioselective reduction of prochiral ketones, see (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219.