2-(Phenylsulfonyl)acetophenone

• Catalog No.: L05032
• CAS Number: 3406-03-9
• M. F.: C14H12O3S
• M. W.: 260.30828
• Purity: 99%

SYNONYMS

• Title: 2-(苯基磺酰)苯乙酮
• IUPAC name: 2-(benzenesulfonyl)-1-phenylethan-1-one
• IUPAC Traditional name: 2-(benzenesulfonyl)-1-phenylethanone
• Synonyms: 2-(Benzenesulfonyl)acetophenone; Phenacyl phenyl sulfone

DATABASE IDS

• Beilstein Number: 1879574
• CAS Number: 3406-03-9
• EC Number: 222-292-0
• MDL Number: MFCD00025043

PROPERTIES

• Purity: 99%
• Melting Point: 92-96°C
• TSCA Listed: 否

REFERENCES

• ?-Keto sulfones can be metallated, e.g. with NaH or LDA. K₂CO₃ in DMF is also effective, e.g. in dialkylation with 1,2-dibromoethane to give a cyclopropane derivative: Synth. Commun., 18, 1433 (1988). The product can be cleaved to the sulfur-free cyclopropyl ketone with Raney nickel.