Diethyl allylmalonate

• Catalog No.: L02286
• CAS Number: 2049-80-1
• M. F.: C10H16O4
• M. W.: 200.23164
• Purity: 97%

SYNONYMS

• Title: 烯丙基丙二酸二乙酯
• IUPAC name: 1,3-diethyl 2-(prop-2-en-1-yl)propanedioate
• IUPAC Traditional name: 1,3-diethyl 2-(prop-2-en-1-yl)propanedioate
• Synonyms: Allylmalonic acid diethyl ester

DATABASE IDS

• EC Number: 218-072-9
• Beilstein Number: 1709466
• CAS Number: 2049-80-1
• MDL Number: MFCD00009155

PROPERTIES

• Purity: 97%
• Boiling Point: 222-223°C
• Density: 1.016
• Flash Point: 92°C(197°F)
• Refractive Index: 1.4310
• GHS Hazard statements: H227
• European Hazard Symbols: Irritant (Xi)
• GHS Precautionary statements: P210-P280-P370+P378A-P403+P235-P501A
• Risk Statements: 36/37/38
• Safety Statements: 26-37-60
• TSCA Listed: 是

REFERENCES

• Alkylation at the one available acidic hydrogen, followed by removal of the allyl group with the reagent (²-propene)Ti(O-i-Pr)₂, readily prepared from Ti(O-i-Pr)₄ and i-PrMgCl, gives the mono-alkyl malonate. Diethyl allylmalonate can thus be regarded as a mono-protected form of diethyl malonate: J. Org. Chem., 61, 2266 (1996):