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Benzhydryl bromide

Catalog No. L02211 Name Alfa Aesar
CAS Number 776-74-9 Website
M. F. C13H11Br Telephone
M. W. 247.13044 Fax
Purity 90+% Email
Storage Chembase ID: 92011

SYNONYMS

Title
二苯甲基溴
IUPAC name
[bromo(phenyl)methyl]benzene
IUPAC Traditional name
bromodiphenylmethane
Synonyms
Bromodiphenylmethane
Diphenylmethyl bromide

DATABASE IDS

EC Number 212-279-8
MDL Number MFCD00000134
CAS Number 776-74-9
Beilstein Number 638544

PROPERTIES

Purity 90+%
Boiling Point 183-185°C/20mm
Flash Point >110°C(230°F)
Melting Point 36-41°C
GHS Pictograms GHS05
GHS Hazard statements H314-H318
European Hazard Symbols Corrosive Corrosive (C)
GHS Precautionary statements P280-P305+P351+P338-P309-P310
Risk Statements 34
RTECS PA5350000
Safety Statements 26-36/37/39-45
Storage Warning Moisture Sensitive
TSCA Listed
Hazard Class 8
UN Number UN1770
Packing Group II

DETAILS

REFERENCES

  • Compare also Benzhydrol, A12884.
  • The benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis: Synth. Commun., 21, 611 (1991).