S,S-Dimethyl-N-(p-toluenesulfonyl)sulfoximine

• Catalog No.: L00577
• CAS Number: 22236-45-9
• M. F.: C9H13NO3S2
• M. W.: 247.33442
• Purity: 98%

SYNONYMS

• Title: S,S-二甲基-N-(对甲苯磺酰基)磺基肟
• IUPAC name: dimethyl[(4-methylbenzenesulfonyl)imino]-λ^6-sulfanone
• IUPAC Traditional name: dimethyl[(4-methylbenzenesulfonyl)imino]-λ^6-sulfanone
• Synonyms: N-(p-Toluenesulfonyl)dimethylsulfoximine

DATABASE IDS

• EC Number: 244-861-2
• CAS Number: 22236-45-9
• MDL Number: MFCD00013922
• Beilstein Number: 2119329

PROPERTIES

• Purity: 98%
• Melting Point: 167-169°C
• TSCA Listed: 否

REFERENCES

• Methylene-transfer agent. For reviews, see: Acc. Chem. Res., 6, 341 (1973); Chem. Soc. Rev., 4, 189 (1975). The anion adds to carbonyl compounds to give epoxides which can react with a further mole of reagent with ring expansion to give 2,2-disubstituted oxetanes: J. Am. Chem. Soc., 101, 6135 (1979); 105, 252 (1983):