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Di-tert-butyl azodicarboxylate_Molecular_structure_CAS_870-50-8)
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Di-tert-butyl azodicarboxylate

Catalog No. L00294 Name Alfa Aesar
CAS Number 870-50-8 Website
M. F. C10H18N2O4 Telephone
M. W. 230.26092 Fax
Purity 98% Email
Storage Chembase ID: 89999

SYNONYMS

Title
偶氮二羧酸二叔丁酯
IUPAC name
(E)-N-{[(tert-butoxy)carbonyl]imino}(tert-butoxy)formamide
IUPAC Traditional name
(E)-N-[(tert-butoxycarbonyl)imino](tert-butoxy)formamide
Synonyms
Azodicarboxylic acid di-tert-butyl ester
DTAD

DATABASE IDS

CAS Number 870-50-8
EC Number 212-796-9
Beilstein Number 1911434
MDL Number MFCD00015001

PROPERTIES

Purity 98%
Melting Point 89-92°C
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P261-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
Safety Statements 26-37
Storage Warning Light Sensitive
TSCA Listed

DETAILS

REFERENCES

  • Aza-dienophile. The ester groups are readily removed from adducts by acid: J. Org. Chem., 26, 4336 (1961); 38, 2043 (1973); 40, 563 (1975).
  • Useful "NH2+" synthon for enantioselective amination reactions: J. Am. Chem. Soc., 108, 6394, 6395, 6397 (1986); Tetrahedron Lett., 29, 6765 (1988).
  • Mitsunobu reaction with alcohols gives a direct route to the corresponding N,N'-di-Boc protected hydrazine derivatives: Tetrahedron Lett., 37, 4327 (1996).