1,2-Phenylene phosphorotrichloridite

• Catalog No.: L00227
• CAS Number: 2007-97-8
• M. F.: C6H4Cl3O2P
• M. W.: 245.427521
• Purity: 94%

SYNONYMS

• Title: 1,2-亚苯基-三次氯酸化膦
• IUPAC name: 2,2,2-trichloro-2H-1,3,2λ^5-benzodioxaphosphole
• IUPAC Traditional name: 2,2,2-trichloro-1,3,2λ^5-benzodioxaphosphole
• Synonyms: Catechyl phosphorus trichloride; 2,2,2-Trichloro-1,3,2-benzodioxaphosphole

DATABASE IDS

• EC Number: 217-913-7
• CAS Number: 2007-97-8
• Beilstein Number: 743959
• MDL Number: MFCD00014578

PROPERTIES

• Safety Statements: 20-26-36/37/39-45
• Storage Warning: Moisture Sensitive
• TSCA Listed: 否
• Hazard Class: 8
• UN Number: UN3261
• Packing Group: II
• GHS Hazard statements: H314-H318
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P260-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501A
• Risk Statements: 34
• Purity: 94%
• Boiling Point: 102-104°C/2mm
• Melting Point: 40-58°C

REFERENCES

• Reagent for conversion of carboxylic acids and esters to acyl chlorides, carbonyl compounds to gem-dichlorides and amides to nitriles: Chem. Ber., 96, 1387 (1963).
• Superior to P₂O₅ for conversion of medium-ring ketones to 1-chlorocycloalkenes: Chem. Ber., 99, 1414 (1966).