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Dibenzyl diethylphosphoramidite_Molecular_structure_CAS_67746-43-4)
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Dibenzyl diethylphosphoramidite

Catalog No. B25619 Name Alfa Aesar
CAS Number 67746-43-4 Website
M. F. C18H24NO2P Telephone
M. W. 317.362421 Fax
Purity 90+% Email
Storage Chembase ID: 149690

SYNONYMS

Title
二苄基二乙基胺基膦
IUPAC name
[bis(benzyloxy)phosphanyl]diethylamine
IUPAC Traditional name
[bis(benzyloxy)phosphanyl]diethylamine
Synonyms
DDP

DATABASE IDS

MDL Number MFCD00191987
CAS Number 67746-43-4

PROPERTIES

Purity 90+%
Density 1.060
Flash Point 73°C(163°F)
Refractive Index 1.5450
GHS Pictograms GHS07
GHS Hazard statements H315-H319-H335-H227
European Hazard Symbols Irritant Irritant (Xi)
GHS Precautionary statements P210-P305+P351+P338-P302+P352-P321-P405-P501A
Risk Statements 36/37/38
Safety Statements 26-37
Storage Warning Moisture Sensitive
TSCA Listed

DETAILS

REFERENCES

  • Phosphitylating agent which reacts with an alcohol under mild conditions. Subsequent oxidation, e.g. with hydrogen peroxide, followed by hydrogenolysis of the benzyl groups, affords the alkyl phosphate: Tetrahedron, 47, 2643 (1991); J. Org. Chem., 59, 7182 (1994). This sequence provides a convenient route to glycosyl phosphates via the glycosyl phosphites: J. Am. Chem. Soc.115, 2260 (1993).